Synthesis, characterization and photophysics of a new series of anionic C,N,C cyclometalated platinum complexes

被引：62

作者：

Berenguer, Jesus R. ^{[1
]}

Lalinde, Elena ^{[1
]}

Torroba, Javier ^{[1
]}

机构：

[1] Univ La Rioja, UA CSIC, Dept Quim, Grp Sintesis Quim La Rioja, Logrono 26006, Spain

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 23期

关键词：

D O I：

10.1021/ic701298z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel series of anionic mononuclear terdentate dicyclometalated complexes (NBu4)[Pt(C boolean AND N boolean AND C)X] (HC boolean AND N boolean AND CH = 2,6-diphenylpyridine) containing acetylide (X = C CR, R = Bu-t, 1; Ph, 2; Tol, 3; (4-OMe)C6H4, 4) or another anionic ligand (X = CN, 5; S-2Py, 6; CH2COCH3, 7) have been synthesized and fully characterized. The solid-state structures of complexes 1 and 4-6 have also been determined by X-ray diffraction studies, showing, in all the cases, the presence of several types of weak hydrogen interactions, leading to the generation of supramolecular 2D (1) or 3D (4-6) architectures. All the complexes (1-7) are intensely luminescent at low temperature (solid and glassy CH2Cl2), exhibiting concentration dependence in the emissions of the glassy CH2Cl2 matrix.

引用

页码：9919 / 9930

页数：12

共 50 条

[31] A new synthesis method and photophysical properties of Ir(C∧N)3 cyclometalated iridium phosphorescent complexes
Chang, Q. -W.
Lie, J.
Yan, C. -X.
Jiang, J.
Chen, J. -L.
Yee, Q. -S.
Yu, J.
Liu, W. -P.
BULGARIAN CHEMICAL COMMUNICATIONS, 2016, 48 (03): : 532 - 534
[32] Synthesis and Characterization of Cyclometalated NHC Platinum Complexes with Chelating Carboxylate Ligands
Zabransky, Martin
Soellner, Johannes
Horky, Filip
Cisarova, Ivana
Stepnicka, Petr
Strassner, Thomas
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (17) : 2284 - 2290
[33] Synthesis, characterization and biological application of cyclometalated heteroleptic platinum(II) complexes
Lunagariya, Miral V.
Thakor, Khyati P.
Patel, Nikita J.
Patel, Mohan N.
APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (02)
[34] Synthesis and Electroluminescence Characterization of Mixed-C∧N Ligand Tris-cyclometalated Ir(III) Complexes
Ma Xiaoyu
Liang Jie
Ye Ling
Fan Yong
Xu Jianing
Ye Kaiqi
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2018, 39 (10): : 2129 - 2135
[35] Novel redox responsive chiral cyclometalated platinum(II) complexes with pinene functionalized C∧N∧N ligands
Zhang, Xiao-Peng
Liu, Fu-Qiang
Lai, Jian-Cheng
Li, Cheng-Hui
Li, Ai-Min
You, Xiao-Zeng
NEW JOURNAL OF CHEMISTRY, 2016, 40 (03) : 2628 - 2636
[36] Electronic structures and photophysical properties of phosphorescent platinum (II) complexes with tridentate C∧N*N cyclometalated ligands
Li, Wenqian
Wang, Jian
Yan, Xi
Zhang, Huize
Shen, Wei
APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (01)
[37] The synthesis of cyclometalated platinum(II) complexes with benzoaryl-pyridines as C∧N ligands for investigating their photophysical, electrochemical and electroluminescent properties
Wang, Dezhi
Chen, Xi
Yang, Hua
Zhong, Daokun
Liu, Boao
Yang, Xiaolong
Yue, Ling
Zhou, Guijiang
Ma, Miaofeng
Wu, Zhaoxin
DALTON TRANSACTIONS, 2020, 49 (44) : 15633 - 15645
[38] Synthesis, characterization, and photophysics of CCC-NHC pincer Platinum complexes
Zhang, Min
Autry, Shane
Dixit, Vivek
Dornshuld, Eric
Denny, Jason
Hammer, Nathan
Webster, Charles
Hollis, T.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[39] Synthesis and photophysics of a series of fac tris homoleptic C∧N3Ir(III) and bis-cyclometalated C∧N2Ir(III)LX complexes for use as dopants in blue emitting devices.
Alleyne, BD
Adamovich, V
Brooks, J
Djurovich, PI
Thompson, ME
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U680 - U680
[40] Synthesis and Photophysics of the Doubly Cyclometalated Pd(II) Complexes [Pd(C∧N∧C)(L)], L = PPh3, AsPh3, and SbPh3
Jordan, Rose
Kler, Sam
Maisuls, Ivan
Klosterhalfen, Niklas
Dietzek-Ivansic, Benjamin
Strassert, Cristian A.
Klein, Axel
INORGANIC CHEMISTRY, 2025, 64 (13) : 6561 - 6574

← 1 2 3 4 5 →