Base-catalysed oxidative [3+2]cycloaddition reaction of [60]fullerene with beta-dicarbonyl compounds

被引：32
|
作者：
Ohno, M [1 ]
Yashiro, A [1 ]
Eguchi, S [1 ]
机构：
[1] NAGOYA UNIV, FAC ENGN, INST APPL ORGAN CHEM, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN
来源：
CHEMICAL COMMUNICATIONS | 1996年 / 03期
关键词：
D O I：
10.1039/cc9960000291
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ambiphilic nature of beta-keto esters and beta-diketones allows cycloaddition to C-60 in the presence of piperidine to give dihydrofuran-fused C-60 derivatives via oxidative cyclization complimentary to the concerted process.
引用
收藏
页码：291 / 292
页数：2
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