Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I)

被引：9

作者：

Lorenzini, Fabio ^{[1
]}

Patrick, Brian O. ^{[1
]}

James, Brian R. ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

DALTON TRANSACTIONS | 2007年 / 30期

关键词：

D O I：

10.1039/b706691k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The water-soluble Rh-1-THP complexes: RhCl(1,5-cod)(THP) (1), [Rh(1,5-cod)(THP)(2)]Cl (2), RhCl(THP)4 (3), and trans-RhCl(CO)(THP)(2) (4) have been synthesized and characterized, where THP = P(CH2OH)(3); 1-3 are the first potentially useful entries into Rh-1-THP chemistry, while 1 and 4 are the first structurally characterized Rh-1-THP complexes.

引用

页码：3224 / 3226

页数：3

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