Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I)

被引：9
|
作者：
Lorenzini, Fabio [1 ]
Patrick, Brian O. [1 ]
James, Brian R. [1 ]
机构：
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
来源：
DALTON TRANSACTIONS | 2007年 / 30期
关键词：
D O I：
10.1039/b706691k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The water-soluble Rh-1-THP complexes: RhCl(1,5-cod)(THP) (1), [Rh(1,5-cod)(THP)(2)]Cl (2), RhCl(THP)4 (3), and trans-RhCl(CO)(THP)(2) (4) have been synthesized and characterized, where THP = P(CH2OH)(3); 1-3 are the first potentially useful entries into Rh-1-THP chemistry, while 1 and 4 are the first structurally characterized Rh-1-THP complexes.
引用
收藏
页码：3224 / 3226
页数：3
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