A Triazolate-Supported Fe3(μ 3 -O) Core: Crystal Structure, Fluorescence, and Hirshfeld Surface Analysis

被引：8

作者：

Feng, Chao ^{[1
]}

Zhu, Yu-Qing ^{[1
]}

Xue, Xing-Ying ^{[1
]}

Zhao, Hong ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2016年 / 27卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Fe(III) cluster; Crystal structure; Fluorescence; Hirshfeld surface analysis; LONE PAIR-PI; INTERMOLECULAR INTERACTIONS; MAGNETIC-PROPERTIES; WEAK FORCES; X-RAY; MOLECULAR-STRUCTURE; TERNARY-SYSTEM; COMPLEXES M; ANION-PI; CLUSTER;

D O I：

10.1007/s10876-016-0989-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One new trinuclear Fe(III) cluster with a Fe-3(mu (3)-O) core was synthesized by the method of hydrothermal synthesis. The complex [Fe-3(mu (3)-O)(pmta)(6)(H2O)(3)]FeCl4 center dot 2H(2)O (1) (where Hpmta is 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid) was characterized by single-crystal X-ray diffraction methods, elemental analyses, IR spectroscopy, fluorescence and Hirshfeld surface analysis. For complex 1, the crystal structure is extended into 3D structure through N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds. According to the 3D Hirshfeld surface and 2D fingerprint plots, the main interactions in the cluster are the H center dot center dot center dot H, N center dot center dot center dot H and C center dot center dot center dot H contacts.

引用

页码：1181 / 1190

页数：10

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