Syntheses and molecular structures of η3-[(η5-Cp*)(CO)2Fe-AsPC(SiMe3)2]M(CO)2(η5-Cp) (M = Mo,W):: the first complexes featuring η3-arsaphosphaallyl ligands

被引：7

作者：

Weber, L ^{[1
]}

Bayer, P ^{[1
]}

Stammler, HG ^{[1
]}

Neumann, B ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 12期

关键词：

D O I：

10.1039/b414621b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of (eta(5)-Cp)(CO)(2)M=P=C(SiMe3)(2) 4a (M = Mo) and 4b (M=W) with (eta(5)- Cp*)(CO)(2)Fe -As=C(NMe2)(2) 5 affords the eta(3)- 1- arsa- 2- phosphaallyl complexes [(eta(5)- Cp*)(CO)(2)Fe AsPC( SiMe3)(2)] M(CO)(2)(eta(5)-Cp) 6a and 6b, the molecular structures of which were determined by X-ray analyses.

引用

页码：1595 / 1597

页数：3

共 50 条

[1] Density functional studies of [{Mo(η5-Cp)(CO)2}2(μ-H)(μ-PMe2)], [{Mo(η5-Cp)(CO)2}2(μ-PMe2)]- and [{Mo(η5-Cp)(CO)3}2]:: Do the metal-metal bonds exist?
Hong, FE
Chang, YC
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2004, 77 (01) : 115 - 121
[2] Density Functional Studies of [{Mo(η5-Cp)(CO) 2}2(μ-H)(μ-PMe2)], [{Moη 5-CP)(CO)2}2(μ-PMe2)]- and [{Mo(η 5-CP)(CO)3}2]: Do the Metal-Metal Bonds Exist?
Hong, F.-E. (fehong@dragon.nchu.edu.tw), 1600, Chemical Society of Japan (77):
[3] Synthesis and structure of the cluster Fe2Mo2(μ3-Se)(μ3-AsMe)(μ3-Co)(μ-Co)(Co)5(η5-Cp)2
S. N. Konchenko
A. V. Virovets
P. A. Petrov
S. V. Tkachev
Russian Chemical Bulletin, 1999, 48 : 988 - 990
[4] Synthesis and structure of the cluster Fe2Mo2(μ3-Se) (μ3-AsMe)(μ3-CO)(μ-CO)(CO)5(η5-Cp)2
Konchenko, SN
Virovets, AV
Petrov, PA
Tkachev, SV
RUSSIAN CHEMICAL BULLETIN, 1999, 48 (05) : 988 - 990
[5] Synthesis, characterization and crystal structures of heterometallic trinuclear carbonyl sulfido clusters (η5-Cp)MoFeCo- (CO)8(μ3-S) and [(η5-Cp)Mo]2Fe(CO)7(μ3-S)
Feng Xu
Wen-Hua Sun
Shi-Yan Yang
Yan-Qi Yin
Qin-Jin Wu
Kai-Bei Yu
Transition Metal Chemistry, 1997, 22 : 176 - 179
[6] Nitrosyl Complexes 6.Reactions of Na[Fe（CO）3NO]with Cp*M（CO）3Cl（Cp*=η5-CH3C5H4,M=Mo or W）:Crystal structures of Cp*M（CO）2NO and Cp*M（μ3-NH）(μ2-NO)（μ2-CO）Fe2（CO）6
SUN
ChineseJournalofChemistry, 1993, (02) : 151 - 158
[7] ELECTROCHEMISTRY OF [M(CO)3CP]2, [M(CO)3CP]+, [M(CO)3CP]-, AND M(CO)3CP WHERE M = MO AND W
KADISH, KM
LACOMBE, DA
ANDERSON, JE
INORGANIC CHEMISTRY, 1986, 25 (13) : 2246 - 2250
[8] SYNTHESES OF CLOSO-CP'(2)(CO)(3)FE(2)MS(2) CLUSTERS (CP'=ETA(5)-C(5)ME(5) M=FE, RU) AND MOLECULAR-STRUCTURE OF CP'(2)(CO)(3)FE3S2
MITSUI, T
INOMATA, S
OGINO, H
INORGANIC CHEMISTRY, 1994, 33 (22) : 4934 - 4936
[9] Reactions of M(CCCCR)(CO)3Cp [M= Mo, W; R= H, Fe(CO)2Cp, M(CO)3Cp] with cobalt carbonyls:: X-ray structures of {Cp(OC)8Co2M(μ3-C)}CC{(μ3-C)Co2M′(CO)8Cp} (M = M′ = Mo, W; M= Mo, M′ = W)
Bruce, MI
Halet, JF
Kahlal, S
Low, PJ
Skelton, BW
White, AH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 578 (1-2) : 155 - 168
[10] Synthesis, characterization and crystal structures of osmium-rhodium mixed-metal clusters containing pentamethylcyclopentadienyl ligand:: [Os3Rh(μ-CO)2(CO)9(η5-Cp*)], [Os3Rh2(μ-H)(μ-CO)2(CO)8(η5-Cp*)(μ2-η5,η1-CH2C5Me4)] and [Os3Rh(μ3-H)(μ-Cl) (μ-CO)(CO)9(η5-Cp*)]
Hung, SYW
Wong, WT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (01) : 48 - 55

← 1 2 3 4 5 →