Through-Space Ligand Interactions in Enantiomeric Dinuclear Ru Complexes

被引：18

作者：

Planas, Nora ^{[1
]}

Christian, Gemma J. ^{[1
]}

Mas-Marza, Elena ^{[1
]}

Sala, Xavier ^{[1
]}

Fontrodona, Xavier ^{[2
]}

Maseras, Feliu ^{[1
,3
]}

Llobet, Antoni ^{[1
,3
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Univ Girona, Serv Tecn, Girona 17071, Spain

[3] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 27期

关键词：

N ligands; NMR spectroscopy; ruthenium; structure elucidation; WATER OXIDATION; BLUE DIMER; DIOXYGEN;

D O I：

10.1002/chem.201000585

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular twisting: A family of dinuclear Ru complexes of general formula [{Ru(T)(L)}2(μ-bpp)](n+1)+ (T = tridentate meridional ligand; bpp = tetradentate bridging ligand and L = monodentate ligand, n = 1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7965 / 7968

页数：4

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