Solvent codeposition and cis-trans isomerization of isophthalic acid derivatives studied by STM

被引：125

作者：

Vanoppen, P ^{[1
]}

Grim, PCM ^{[1
]}

Rucker, M ^{[1
]}

DeFeyter, S ^{[1
]}

Moessner, G ^{[1
]}

Valiyaveettil, S ^{[1
]}

Mullen, K ^{[1
]}

DeSchryver, FC ^{[1
]}

机构：

[1] KATHOLIEKE UNIV LEUVEN,DEPT CHEM,LAB MOL DYNAM & SPECT,B-3001 HEVERLEE,BELGIUM

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 50期

关键词：

D O I：

10.1021/jp962737+

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Scanning tunneling microscopy (STM) was used to study physisorbed monolayers of 5-octadecyloxyisophthalic acid (C(18)ISA) and 5-[omega-(4'-dodecyloxy-4-azobenzeneoxy)dodecyloxy]isophthalic acid (C-12(AZO)C(12)ISA) at a liquid/graphite interface. The acquired STM images exhibit the molecular packing of the monolayers with submolecular resolution. Monolayers formed by codeposition of solvent molecules and C(18)ISA or C-12(AZO)C-12- ISA molecules are found when 1-octanol and 1-undecanol are used as a solvent. The cis and trans isomers of C-12(AZO)C(12)ISA, the reagent and reaction product of a reversible photoinduced reaction, are simultaneously present and are both structurally identified at the liquid/graphite interface.

引用

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页码：19636 / 19641

页数：6

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