Solvent codeposition and cis-trans isomerization of isophthalic acid derivatives studied by STM

被引：125

作者：

Vanoppen, P ^{[1
]}

Grim, PCM ^{[1
]}

Rucker, M ^{[1
]}

DeFeyter, S ^{[1
]}

Moessner, G ^{[1
]}

Valiyaveettil, S ^{[1
]}

Mullen, K ^{[1
]}

DeSchryver, FC ^{[1
]}

机构：

[1] KATHOLIEKE UNIV LEUVEN,DEPT CHEM,LAB MOL DYNAM & SPECT,B-3001 HEVERLEE,BELGIUM

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 50期

关键词：

D O I：

10.1021/jp962737+

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Scanning tunneling microscopy (STM) was used to study physisorbed monolayers of 5-octadecyloxyisophthalic acid (C(18)ISA) and 5-[omega-(4'-dodecyloxy-4-azobenzeneoxy)dodecyloxy]isophthalic acid (C-12(AZO)C(12)ISA) at a liquid/graphite interface. The acquired STM images exhibit the molecular packing of the monolayers with submolecular resolution. Monolayers formed by codeposition of solvent molecules and C(18)ISA or C-12(AZO)C-12- ISA molecules are found when 1-octanol and 1-undecanol are used as a solvent. The cis and trans isomers of C-12(AZO)C(12)ISA, the reagent and reaction product of a reversible photoinduced reaction, are simultaneously present and are both structurally identified at the liquid/graphite interface.

引用

页码：19636 / 19641

页数：6

共 50 条

[1] SOLVENT EFFECTS IN CIS-TRANS ISOMERIZATION
LUNER, P
WINKLER, CA
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1952, 30 (09): : 679 - 686
[2] PHOTOCHEMICAL CIS-TRANS ISOMERIZATION OF TRIAZABUTADIENE DERIVATIVES
FANGHANE.E
HANSEL, R
ORTMANN, W
[J]. ZEITSCHRIFT FUR CHEMIE, 1974, 14 (08): : 328 - 328
[3] ENZYMIC CIS-TRANS ISOMERIZATION OF MALEYLPYRUVIC ACID
LACK, L
[J]. JOURNAL OF BIOLOGICAL CHEMISTRY, 1961, 236 (11) : 2835 - &
[4] Cis-Trans isomerization mechanisms of muconic acid
Zaczek, Adam
Korter, Tim
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
[5] CIS-TRANS ISOMERIZATION OF OLEIC ACID BY NITROUS ACID
LITCHFIE.C
HARLOW, RD
ISBELL, AF
REISER, R
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1965, 42 (02) : 73 - &
[6] CIS-TRANS ISOMERIZATION OF OLEIC ACID BY NITROUS ACID
LITCHFIELD, C
HARLOW, RD
ISBELL, AF
REISER, R
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1964, 41 (03) : 26 - &
[7] CIS-TRANS ISOMERIZATION OF SOME SIMPLE ETHYLENE DERIVATIVES
CRUMP, JW
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (04): : 953 - &
[8] KINETICS OF A CIS-TRANS ISOMERIZATION IN A HEAVY-ATOM SOLVENT
MCCOY, EF
PARFITT, SSG
ROSS, IG
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (08): : 1079 - 1080
[9] CIS-TRANS ISOMERIZATION OF DIFLUORODIAZINE
BINENBOY.J
BURCAT, A
LIFSHITZ, A
SHAMIR, J
[J]. ISRAEL JOURNAL OF CHEMISTRY, 1966, 4 (1A) : P34 - &
[10] CIS-TRANS ISOMERIZATION OF CROCIN
AGATI, G
FUSI, F
PRATESI, R
MANITTO, P
SPERANZA, G
MONTI, D
[J]. QUANTUM ELECTRONICS AND PLASMA PHYSICS: 5TH ITALIAN CONFERENCE, 1989, 21 : 365 - 368

← 1 2 3 4 5 →