Bottom-Up Assembly from a Helicate to Homochiral Micro- and Mesoporous Metal-Organic Frameworks

被引：85
|
作者：
Xi, Xiaobing [1 ,2 ]
Fang, Yu [1 ,2 ]
Dong, Taiwei [1 ,2 ]
Cui, Yong [1 ,2 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
[2] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 05期
关键词：
bottom-up assembly; chirality; metal-organic frameworks; porosity; supramolecular chemistry; BUILDING-BLOCKS; ENANTIOSELECTIVE SEPARATION; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; HYDROGEN UPTAKE; ZEOLITE; CATALYSIS; MOLECULE; POROSITY; SOLVENT;
D O I：
10.1002/anie.201004885
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In triple time: A step-by-step assembly of three homochiral micro- and mesoporous metal-organic frameworks (MOFs) from a predesigned triple-stranded heptametallic helicate bearing six free pyridine groups has been achieved. The geometry, symmetry, and enantiopurity of the helicate are efficiently amplified in the infinite frameworks. Furthermore, the MOFs can encapsulate guest molecules (see example). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1154 / 1158
页数：5
相关论文
共 50 条
  • [1] Micro- and mesoporous metal-organic frameworks for hydrocarbon separation
    Kovalenko, Konstantin A.
    Potapov, Andrei S.
    Fedin, Vladimir P.
    [J]. RUSSIAN CHEMICAL REVIEWS, 2022, 91 (04)
  • [2] Hierarchically Micro- and Mesoporous Metal-Organic Frameworks with Tunable Porosity
    Qiu, Ling-Guang
    Xu, Tao
    Li, Zong-Qun
    Wang, Wei
    Wu, Yun
    Jiang, Xia
    Tian, Xing-You
    Zhang, Li-De
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (49) : 9487 - 9491
  • [3] Bottom-up realization of a porous metal-organic nanotubular assembly
    Otsubo, Kazuya
    Wakabayashi, Yusuke
    Ohara, Jun
    Yamamoto, Shoji
    Matsuzaki, Hiroyuki
    Okamoto, Hiroshi
    Nitta, Kiyofumi
    Uruga, Tomoya
    Kitagawa, Hiroshi
    [J]. NATURE MATERIALS, 2011, 10 (04) : 291 - 295
  • [4] Bottom-up realization of a porous metal-organic nanotubular assembly
    Otsubo K.
    Wakabayashi Y.
    Ohara J.
    Yamamoto S.
    Matsuzaki H.
    Okamoto H.
    Nitta K.
    Uruga T.
    Kitagawa H.
    [J]. Nature Materials, 2011, 10 (4) : 291 - 295
  • [5] Bottom-up assembly of self-supporting metal-organic layers
    Cao, Lingyun
    Wang, Cheng
    Lin, Wenbin
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [6] Hydrolytic Transformation of Microporous Metal-Organic Frameworks to Hierarchical Micro- and Mesoporous MOFs
    Kim, Yonghwi
    Yang, Tao
    Yun, Gyeongwon
    Ghasemian, Mohammad Bagher
    Koo, Jaehyoung
    Lee, Eunsung
    Cho, Sung June
    Kim, Kimoon
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (45) : 13273 - 13278
  • [7] Downsizing metal-organic frameworks by bottom-up and top-down methods
    Usman, Ken Aldren S.
    Maina, James W.
    Seyedin, Shayan
    Conato, Marlon T.
    Payawan, Leon M., Jr.
    Dumee, Ludovic F.
    Razal, Joselito M.
    [J]. NPG ASIA MATERIALS, 2020, 12 (01)
  • [8] Bottom-Up Assembly of a Highly Efficient Metal-Organic Framework for Cooperative Catalysis
    Li, Changda
    Tang, Haitong
    Fang, Yu
    Xiao, Zhifeng
    Wang, Kunyu
    Wu, Xiang
    Niu, Helin
    Zhu, Chengfeng
    Zhou, Hong-cai
    [J]. INORGANIC CHEMISTRY, 2018, 57 (21) : 13912 - 13919
  • [9] Application of Consistency Criteria To Calculate BET Areas of Micro- And Mesoporous Metal-Organic Frameworks
    Gomez-Gualdron, Diego A.
    Moghadam, Peyman Z.
    Hupp, Joseph T.
    Farha, Omar K.
    Snurr, Randall Q.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (01) : 215 - 224
  • [10] Homochiral metal-organic frameworks for enantioseparation
    Liu, Juan
    Mukherjee, Soumya
    Wang, Fei
    Fischer, Roland A.
    Zhang, Jian
    [J]. CHEMICAL SOCIETY REVIEWS, 2021, 50 (09) : 5706 - 5745
12345