Hierarchically Micro- and Mesoporous Metal-Organic Frameworks with Tunable Porosity

被引:353
|
作者
Qiu, Ling-Guang [1 ]
Xu, Tao [1 ]
Li, Zong-Qun [1 ]
Wang, Wei [1 ]
Wu, Yun [1 ]
Jiang, Xia [1 ]
Tian, Xing-You [2 ]
Zhang, Li-De [2 ]
机构
[1] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Peoples R China
基金
中国国家自然科学基金;
关键词
mesoporous materials; metal-organic frameworks; microporous materials; organic-inorganic hybrid composites; zeolite analogues;
D O I
10.1002/anie.200803640
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) A new hierarchy: A supramolecular template strategy is used to synthesize hierarchical micro- and mesoporous metal-organic frameworks. The mesopore walls are constructed from a microporous framework (see picture). The porosity can be tuned by using different templates at various molar ratios. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:9487 / 9491
页数:5
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