Basic functionalized ionic liquid catalyzed one-pot Mannich-type reaction:: Three component synthesis of β-amino carbonyl compounds

被引：56
|
作者：
Gong, Kai [1 ]
Fang, Dong [1 ]
Wang, Hua-Lan [1 ]
Liu, Zu-Liang [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing, Peoples R China
来源：
MONATSHEFTE FUR CHEMIE | 2007年 / 138卷 / 11期
关键词：
Mannich-type reaction; ionic liquid; catalyst; one-pot reaction;
D O I：
10.1007/s00706-007-0767-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three-component Mannich-type reaction of cyclohexanone, aromatic aldehydes, and aromatic amines was catalyzed by a basic functionalized ionic liquid, 1-butyl-3-methylimidazolium hydroxide ([bmim] [OH]), at room temperature to give various beta-amino carbonyl compounds in high yields. The ionic liquid, which is environmentally friendly, can be recycled at least 5 times without significant loss of activity.
引用
收藏
页码：1195 / 1198
页数：4
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