Copper-Catalyzed NaBAr 4 -Based N-Arylation of Amines

被引：6
|
作者：
Yang, Qin
Lei, Xiaoli
Yin, Zhijian
Deng, Zhihong
Peng, Yiyuan [1 ]
机构：
[1] Jiangxi Normal Univ, Key Lab Small Funct Organ Mol, Minist Educ, Nanchang 330022, Jiangxi, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2019年 / 51卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Cham-Lam cross-coupling reaction; amine; copper acetate monohydrate; tetraphenylborate; N-phenylation; CROSS-COUPLING REACTIONS; C-N; ARYLBORONIC ACIDS; ARYL HALIDES; SODIUM TETRAPHENYLBORATE; EFFICIENT CATALYST; COMPLEX; PHENYLATION; AMINATION; METAL;
D O I：
10.1055/s-0037-1610251
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Using NaBAr (4) as an arylating agent, the formation of carbon-heteroatom bonds by a Cham-Lam cross-coupling reaction in the presence of catalytic copper(II) acetate monohydrate in acetonitrile at room temperature under air is described. The investigation of reaction scope suggests that several aliphatic and aromatic amines are compatible. In particular, the reaction of alkylamine and NaBAr (4) proceeds smoothly to offer the corresponding products in good to excellent yields.
引用
收藏
页码：538 / 544
页数：7
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