p(HEMA)-Pd(II) and p(HEMA-MAH)-Pd(II) Microspheres: Efficient, Recyclable and Ligand-Free Catalyst for Suzuki-Miyaura Cross-Coupling Reaction in Water

被引：2
|
作者：
Durap, Feyyaz [1 ,2 ]
Baysal, Akin [1 ]
Elma, Duygu [1 ]
Aydemir, Murat [1 ,2 ]
Ok, Ozge [1 ]
Baysal, Zubeyde [1 ]
机构：
[1] Dicle Univ, Fac Sci, Dept Chem, Diyarbakir, Turkey
[2] Dicle Univ, Sci & Technol Applicat & Res Ctr DUBTAM, Diyarbakir, Turkey
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 09期
关键词：
microspheres; palladium (II); catalyst; Suzuki-Miyaura coupling; water; STABILIZED PALLADIUM NANOPARTICLES; SUPPORTED PALLADIUM; REUSABLE CATALYST; AQUEOUS-SOLUTION; STILLE REACTION; HECK REACTIONS; PD; ADSORPTION; COMPLEXES; HISTIDINE;
D O I：
10.1080/15533174.2015.1136954
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this study, the authors report the synthesis and characterization of new poly(hydroxyethyl methacrylate) palladium(II) (p (HEMA)-Pd(II)) and poly(hydroxyethyl methacrylate-N-methacryloyl-(L)-histidine methyl ester) palladium(II), p(HEMA-MAH)Pd(II) microsphere catalysts, and their catalysis in Suzuki-Miyaura coupling reactions of aryl bromides with phenylboronic acid in water. The microsphere catalysts were characterized by SEM, ICP-MS, FTIR, and diffuse-reflactance UV-visible spectroscopy. The p(HEMA)-Pd(II) and p(HEMA-MAH)-Pd(II) microsphere catalysts were active catalysts in Suzuki-Miyaura coupling reactions of arylbromides with phenylboronic acid affording biphenyls in high yield. Recycling experiments showed that the p(HEMA)-Pd(II) and p(HEMA-MAH)-Pd(II) microsphere catalysts could be used seven or ten times with essentially no loss in activity in the Suzuki-Miyaura coupling reactions.
引用
收藏
页码：1402 / 1409
页数：8
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