Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides

被引：2
|
作者：
Fischer, Roland [1 ]
Marschner, Christoph [1 ]
机构：
[1] Graz Univ Technol, Inst Anogan Chem, A-8010 Graz, Austria
来源：
MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 01期
关键词：
stannylated compounds; group; 4; elements; metallocenes; stannylene; tin; silicon; zirconium; hafnium; DERIVATIVES; MECHANISM; POLYMERIZATION; TRIMETHYLSILYL; POLYSILANES; REACTIVITY; ZIRCONIUM; COMPLEXES; HAFNIUM; SILANES;
D O I：
10.1016/j.mencom.2022.01.016
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of (Me3Si)(3)SnK with Cp2MCl2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp2M(Cl)SiMe3 formation.
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页码：52 / 53
页数：2
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