Syntheses and Crystal Structures of [M(H2O)6](C16H11O4SO3)2•2H2O (M = Zn, Mg, Co)

被引：1

作者：

Ding, Ru ^{[1
,2
]}

Wei, Tao ^{[1
,2
]}

Wang, Qiu-Ya ^{[1
,2
,3
]}

Wang, Tao ^{[1
,2
]}

Zhang, Zun-Ting ^{[1
,2
]}

机构：

[1] Shaanxi Normal Univ, Key Lab, Natl Engn Lab Resource Dev Endangered Crude Drugs, Minist Educ Med Resources & Nat Pharmaceut Chem, Xian 710062, Shaanxi, Peoples R China

[2] Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710062, Shaanxi, Peoples R China

[3] Weinan Normal Univ, Coll Chem & Chem Engn, Xian 71400, Shaanxi, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Pallidiflorin; 5-Hydroxy-4 '-methoxyisoflavone-3 '-sulfonate; Hydrogen bonds; pi-pi stacking; SULFATED FLAVONOIDS; COMPLEXES; COPPER; ZINC;

D O I：

10.1002/zaac.201400601

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sodium 5-hydroxy-4'-methoxyisoflavone-3'-sulfonate was synthesized by sulfonation of pallidiflorin and assembled with Zn-II, Mg-II, and Co-II to form [Zn(H2O)(6)](C16H11O4SO3)(2)center dot 2H(2)O (1), [Mg(H2O)(6)](C16H11O4SO3)(2)center dot 2H(2)O (2), and [Co (H2O)(6)] (C16H11O4SO3)(2)center dot 2H(2)O (3). In the crystal structures of 1-3, [M(H2O)(6)](2+), C16H11O4SO3-, and H2O form intermolecular and intramolecular hydrogen bonds. The hydrogen bonds, pi-pi stacking interactions, and electrostatic interactions between the cations and anions link compounds 1-3 into three-dimensional structures. The thermal stabilities of 1-3 were also investigated.

引用

页码：1130 / 1134

页数：5

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