Synthesis, single crystal structure determination, and solution behavior of an 8-hydroxyquinoline derivative of niobium(V) ethoxide

被引：7

作者：

Amini, Mostafa M. ^{[1
]}

Mirzaee, Mehdi ^{[1
]}

Yaganeh, Farnaze ^{[1
]}

Khavasi, Hamid Reza ^{[1
]}

Mirzaei, Peiman ^{[1
]}

Ng, Seik Weng ^{[2
]}

机构：

[1] Shahid Beheshti Univ Med Sci, Dept Chem, Tehran 1983963113, Iran

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

TRANSITION METAL CHEMISTRY | 2008年 / 33卷 / 01期

关键词：

D O I：

10.1007/s11243-007-9017-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An 8-hydroxyquinoline derivative of niobium(V) ethoxide was synthesized and characterized by elemental analysis, mass spectrometry, infrared, electronic, and H-1, C-13, and (NMR)-N-93 spectroscopies. Tetraethoxy(8-quinolinato)niobium(V), as shown by the single crystal structure determination, exists as an octahedral compound in the solid state in which the 8-quinolinato group chelates to the metal atom. In solution, this group partially becomes unidentate; the six-coordinate species is in equilibrium with the five-coordinate species, as shown by Nb-93 and variable-temperature H-1 NMR spectroscopy.

引用

页码：79 / 83

页数：5

共 50 条

[31] Synthesis and antimicrobial activities of sulfonohydrazide-substituted 8-hydroxyquinoline derivative and its oxinates
Dixit, Ritu B.
Vanparia, Satish F.
Patel, Tarosh S.
Jagani, Chandresh L.
Doshi, Hiren V.
Dixit, Bharat C.
APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (05) : 408 - 413
[32] CRYSTAL AND MOLECULAR STRUCTURE OF PYRIDINE SOLVATE OF BIS(8-HYDROXYQUINOLINE)SILVER(I)
FLEMING, JE
LYNTON, H
CANADIAN JOURNAL OF CHEMISTRY, 1968, 46 (04): : 471 - &
[33] Synthesis, spectroscopic and voltammetric studies of a novel dioxovanadate(V) 8-hydroxyquinoline complex
Çakir, S
Biçer, E
Naumov, P
Çakir, O
JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (12) : 1461 - 1471
[34] The effects of crystal structure on optical absorption/photoluminescence of bis(8-hydroxyquinoline)zinc
Xu, BS
Hao, YY
Wang, H
Zhou, HF
Liu, XG
Chen, MW
SOLID STATE COMMUNICATIONS, 2005, 136 (06) : 318 - 322
[35] Synthesis, crystal structure, and vibrational and magnetic properties of Co(II) and Hg(II) complexes with an 8-hydroxyquinoline unit
Ben Debabis, Rim
Amamou, Walid
Chniba-Boudjada, Nassira
Zouari, Fatma
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2019, 124 : 296 - 304
[36] DETERMINATION OF ALUMINIUM WITH 8-HYDROXYQUINOLINE .I. PRECIPITATION IN ACETATE-BUFFERED SOLUTION
CLAASSEN, A
BASTINGS, L
ANALYST, 1967, 92 (1099) : 614 - &
[37] DETERMINATION OF ALUMINIUM WITH 8-HYDROXYQUINOLINE .2. PRECIPITATION IN AMMONIACAL CYANIDE - EDTA SOLUTION
CLAASSEN, A
BASTINGS, L
VISSER, J
ANALYST, 1967, 92 (1099) : 618 - &
[38] A SENSITIVE SPECTROPHOTOMETRIC DETERMINATION OF NIOBIUM (V) WITH 5,7-DINITRO-8-HYDROXYQUINOLINE
SHARMA, Y
SHIVAHARE, GC
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1980, 27 (03) : 129 - 132
[39] Investigation on growth, structure and characterization of succinate salt of 8-hydroxyquinoline: An organic NLO crystal
Thirumurugan, R.
Babu, B.
Anitha, K.
Chandrasekaran, J.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 140 : 44 - 53
[40] Enantioselective Synthesis of 8-Hydroxyquinoline Derivative, Q134 as a Hypoxic Adaptation Inducing Agent
Hackler, Laszlo
Gyuris, Mario
Huzian, Orsolya
Alfoeldi, Robert
Szebeni, Gabor J.
Madacsi, Ramona
Knapp, Levente
Kanizsai, Ivan
Puskas, Laszlo G.
MOLECULES, 2019, 24 (23):

← 1 2 3 4 5 →