A Luminescent Molecular Thermometer for Long-Term Absolute Temperature Measurements at the Nanoscale

被引:419
|
作者
Brites, Carlos D. S. [3 ,4 ]
Lima, Patricia P. [3 ,4 ]
Silva, Nuno J. O. [3 ,4 ]
Millan, Angel [1 ,2 ]
Amaral, Vitor S. [3 ,4 ]
Palacio, Fernando [1 ,2 ]
Carlos, Luis D. [3 ,4 ]
机构
[1] Univ Zaragoza, CSIC, Dept Fis Mat Condensada, Fac Ciencias, E-50009 Zaragoza, Spain
[2] Univ Zaragoza, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
[3] Univ Aveiro, Dept Fis, P-3810193 Aveiro, Portugal
[4] Univ Aveiro, CICECO, P-3810193 Aveiro, Portugal
关键词
ORGANIC-INORGANIC HYBRIDS; PHOSPHOR; FLUORESCENCE; NANOPARTICLES; EUROPIUM(III); SPECTROSCOPY; CONVERSION; LIFETIME; SENSORS;
D O I
10.1002/adma.201001780
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A unique Eu3+/Tb3+ luminescent self-referencing nanothermometer allowing absolute measurements in the 10-350 K temperature range and sub-micrometer spatial resolution is reported (see Figure). It has up to 4.9%K-1 temperature sensitivity and high photostability for long-term use. The combination of molecular thermometry, superparamagnetism and luminescence in a nanometric host matrix provides multifunctionality opening the way for new exciting applications. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4499 / 4504
页数:6
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