Synthesis, Crystal Structure and Thermal Behavior of a New Polynitrile N,N,N',N'-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine

被引：1

作者：

Xu, Rui-Bo ^{[2
,3
]}

Xu, Xing-You ^{[1
,3
]}

Zhou, Yu-Min ^{[2
]}

Yang, Xu-Jie ^{[3
]}

Ma, Wei-Xing ^{[2
]}

Wang, Da-Qi ^{[4
]}

Huang, Yu-Ping ^{[2
]}

Xu, Chun-Mei ^{[2
]}

机构：

[1] Huaiyin Inst Technol, Huaian 223003, Peoples R China

[2] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222005, Peoples R China

[3] Nanjing Univ Sci & Technol, Minist Educ, Lab Soft Chem & Funct Mat, Nanjing 210094, Peoples R China

[4] Shandong Liaocheng Univ, Dept Chem Engn, Liaocheng 252059, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 08期

关键词：

Polynitrile; N,N,N ',N '-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine; Synthesis; Crystal structure; Thermal behavior; ANTITUMOR-ACTIVITY; AMINES;

D O I：

10.1007/s10870-011-0069-8

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new polynitrile, N,N,N',N'-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine, was synthesized by the nucleophilic addition reaction of 1,4-bis(3-aminopropyl)piperazine and acrylonitrile for the first time. The title compound was characterized by elemental analysis, IR spectrum, and its crystal structure determined by X-ray single-crystal diffraction. The compound crystallizes in the monoclinic system with space group P2 (1)/c and a = 8.6195(12), b = 9.300(14), c = 16.221(2) , beta = 97.824(2)A degrees, V = 1288.2(3) (3), D (c) = 1.064 g cm(-3), M (r) = 412.59, Z = 2, F(000) = 448, mu = 0.067 mm(-1). The TG-DTA analysis revealed that the title compound possesses relatively good thermal stability under 220 A degrees C.

引用

页码：1190 / 1194

页数：5

共 50 条

[41] Synthesis of N-(2-aminoethyl)- and N-(3-aminopropyl)cytisine
D. V. Shishkin
A. N. Lobov
N. Z. Baibulatova
N. M. Vlasova
L. V. Spirikhin
V. A. Dokichev
Chemistry of Natural Compounds, 2012, 48 : 436 - 439
[42] Study of novel bioactive n, n?-bis (3-aminopropyl) piperazine derivatives: Green synthesis, spectral characterization, in silico docking and biological activity
Sriraman, V.
Satheeshkumar, K. S.
Arun, A.
MATERIALS TODAY-PROCEEDINGS, 2022, 60 : 1261 - 1273
[43] SYNTHESIS AND CHARACTERIZATION OF METAL-COMPLEXES WITH SCHIFF-BASES OBTAINED FROM N,N'-BIS(3-AMINOPROPYL)PIPERAZINE AND SALICYLALDEHYDE DERIVATIVES
KUMA, H
YAMADA, S
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (11) : 3218 - 3220
[44] [μ-trans-N,N′-Bis(3-aminopropyl)oxamidato(2-)]-bis[(methanol)picratocopper(II)]
Song, Yu-Lan
Li, Yan-Tuan
Wu, Zhi-Yong
Zhang, Gui-Ling
Sun, Fen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2558 - M2560
[45] Synthesis and Dyeing Performance of N,N-bis(2-cyanoethyl)-m-methylaniline Disperse Dyes
Liu, Wei
Zhao, Ying
Yu, Zehua
Wan, Xiaoqiao
Li, Wenlan
ADVANCES IN CHEMICAL ENGINEERING II, PTS 1-4, 2012, 550-553 : 21 - 26
[46] SYNTHESIS AND STRUCTURE OF BINUCLEAR CU(II)-ZN(II) COMPLEXES WITH N, N'-BIS (3-AMINOPROPYL) OXAMIDO COPPER(II)
LIU, ZM
JIANG, ZH
LIAO, DZ
WANG, GL
YAO, XK
WANG, HG
ACTA CHIMICA SINICA, 1991, 49 (10) : 981 - 986
[47] [μ-N,N′-bis(3-aminopropyl)oxamidato(2-)]-bis[(2,2′-bipyridine)copper(II)] dinitrate
Boyd, Peter D. W.
Rickard, C. E. F.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M3200 - M3202
[48] Synthesis and magnetic properties of copper(Ⅱ)-lanthanoid(Ⅲ) binuclear complexes with N,N'-bis(3-aminopropyl) oxamido ligand
LI
Chinese Journal of Chemistry, 1994, (05) : 414 - 418
[49] Crystal Structure of N,N '-Bis(5-butoxytropon-2-yl)piperazine
Kubo, Kanji
Yamamoto, Emi
Matsumoto, Taisuke
Mori, Akira
X-RAY STRUCTURE ANALYSIS ONLINE, 2016, 32 : 37 - 38
[50] INTERACTIONS IN CUIICUIICUII, CUIIZNIICUII, AND CUIINIIICUII TRINUCLEAR SPECIES - CRYSTAL-STRUCTURE OF BIS(N,N'-BIS(3-AMINOPROPYL)OXAMIDO)TRICOPPER(II) PERCHLORATE
JOURNAUX, Y
SLETTEN, J
KAHN, O
INORGANIC CHEMISTRY, 1986, 25 (04) : 439 - 447

← 1 2 3 4 5 →