Conductivity studies on oxygen-deficient Ruddlesden-Popper phases

被引：19
|
作者：
Navas, C [1 ]
zurLoye, HC [1 ]
机构：
[1] MIT,DEPT CHEM,CAMBRIDGE,MA 01239
来源：
SOLID STATE IONICS | 1996年 / 93卷 / 1-2期
关键词：
Ruddlesden-Popper; oxide; ionic conductivity;
D O I：
10.1016/S0167-2738(96)00515-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new series of doped-Ruddlesden-Popper phases, of general formula Sr(3)M(2-x)M(x)'O-7-y (M = Ti, Zr, M' = Al, Ga, In) were synthesized and their conductivity was investigated as a function of temperature and oxygen partial pressure. The highest total conductivity in air is 1.6 x 10(-3) S/cm at 950 degrees C for both Sr3Ti1.75Ga0.25O6.875 and Sr3Ti1.9In0.1O6.95. Measurements of the conductivity as a function of oxygen partial pressure indicate that p-type electronic conductivity predominates at high p(O-2), while a p(O-2)-independent region at intermediate p(O-2) values indicates ionic conductivity. The magnitude of the ionic conductivity at 700 degrees C is approximately 10(-5) S/cm.
引用
收藏
页码：171 / 176
页数：6
相关论文
共 50 条
  • [21] Is the surface oxygen exchange rate linked to bulk ion diffusivity in mixed conducting Ruddlesden-Popper phases?
    Tomkiewicz, Alex C.
    Tamimi, Mazin A.
    Huq, Ashfia
    McIntosh, Steven
    FARADAY DISCUSSIONS, 2015, 182 : 113 - 127
  • [22] Resonant inelastic x-ray scattering data for Ruddlesden-Popper and reduced Ruddlesden-Popper nickelates
    Fabbris, G.
    Meyers, D.
    Shen, Y.
    Bisogni, V.
    Zhang, J.
    Mitchell, J. F.
    Norman, M. R.
    Johnston, S.
    Feng, J.
    Chiuzbaian, G. S.
    Nicolaou, A.
    Jaouen, N.
    Dean, M. P. M.
    SCIENTIFIC DATA, 2023, 10 (01)
  • [23] Resonant inelastic x-ray scattering data for Ruddlesden-Popper and reduced Ruddlesden-Popper nickelates
    G. Fabbris
    D. Meyers
    Y. Shen
    V. Bisogni
    J. Zhang
    J. F. Mitchell
    M. R. Norman
    S. Johnston
    J. Feng
    G. S. Chiuzbăian
    A. Nicolaou
    N. Jaouen
    M. P. M. Dean
    Scientific Data, 10
  • [24] Tunability of TCF in Ruddlesden-Popper compounds
    Reaney, IM
    Wise, PL
    Lee, WE
    Iddles, DM
    Cannell, DS
    Price, TJ
    PROCEEDINGS OF THE 2001 12TH IEEE INTERNATIONAL SYMPOSIUM ON APPLICATIONS OF FERROELECTRICS, VOLS I AND II, 2001, : 187 - 190
  • [25] Ruddlesden-Popper Perovskite Solar Cells
    Koh, Teck Ming
    Febriansyah, Benny
    Mathews, Nripan
    CHEM, 2017, 2 (03): : 326 - 327
  • [26] Local-electrostatics-induced oxygen octahedral distortion in perovskite oxides and insight into the structure of Ruddlesden-Popper phases
    Hong, Youngjae
    Byeon, Pilgyu
    Bak, Jumi
    Heo, Yoon
    Kim, Hye-Sung
    Bae, Hyung Bin
    Chung, Sung-Yoon
    NATURE COMMUNICATIONS, 2021, 12 (01)
  • [27] A High-Performance Ruddlesden-Popper Perovskite for Bifunctional Oxygen Electrocatalysis
    Liu, Subiao
    Sun, Chong
    Chen, Jian
    Xiao, Jing
    Luo, Jing-Li
    ACS CATALYSIS, 2020, 10 (22): : 13437 - 13444
  • [28] Defect structure and electrical conductivity of the Ruddlesden-Popper phases Sr3FeMO6+δ (M = Co, Ni)
    Mogni, L.
    Prado, F.
    Caneiro, A.
    CHEMISTRY OF MATERIALS, 2006, 18 (17) : 4163 - 4170
  • [29] Predicting switchable multi-ferroic ruddlesden-popper phases & phase transitions
    Howard, Christopher
    Carpenter, Michael
    Kisi, Erich
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C703 - C704
  • [30] Simulation Studies of the Phase Stability of the Srn+1TinO3n+1 Ruddlesden-Popper Phases
    Ramadan, Amr H. H.
    Allan, Neil L.
    De Souza, Roger A.
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (07) : 2316 - 2321
12345