Phosphorylation of Betti Base with Bis(diethylamino)phosphoryl Chloride

被引：2

作者：

Metlushka, K. E. ^{[1
]}

Sadkova, D. N. ^{[1
]}

Nikitina, K. A. ^{[1
]}

Yamaleeva, Z. R. ^{[1
]}

Ivshin, K. A. ^{[1
,2
]}

Kataeva, O. N. ^{[1
]}

Alfonsov, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, FRC Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Ul Akad Arbuzova 8, Kazan 420088, Tatarstan, Russia

[2] Kazan Volga Reg Fed Univ, Butlerov Chem Inst, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 11期

关键词：

Betti base; phosphorylation; thiourea;

D O I：

10.1134/S1070363218110348

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of bis(diethylamino)phosphoryl chloride with N-Boc-protected 1-(-aminobenzyl)-2- naphthol (Betti base) proceeded via O-phosphorylation of the phenolic OH group to form the target product as trifluoroacetate salt. The latter reacted with O,O-diethyl thiophosphorylisothiocyanate to give thiourea bearing a chiral Betti base fragment.

引用

页码：2453 / 2456

页数：4

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