Diastereo- and Enantioselective Intramolecular C(sp3)?H Arylation for the Synthesis of Fused Cyclopentanes

被引：111

作者：

Martin, Nicolas ^{[1
]}

Pierre, Cathleen ^{[1
]}

Davi, Michael ^{[1
]}

Jazzar, Rodolphe ^{[1
]}

Baudoin, Olivier ^{[1
]}

机构：

[1] Univ Lyon 1, Inst Chim & Biochim Mol & Supramol, CPE Lyon, CNRS,UMR 5246, F-69622 Villeurbanne, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 15期

关键词：

asymmetric catalysis; C?C coupling; C?H activation; palladium; C-H ACTIVATION; QUATERNARY STEREOCENTERS; BOND FUNCTIONALIZATION; ORGANIC-SYNTHESIS; ALKANE ARYLATION; C(SP(3))-H BONDS; CHIRAL LIGANDS; DISCOVERY; INDOLINES;

D O I：

10.1002/chem.201200018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

All C-H bonds are not equal: The intramolecular arylation of unactivated C(sp3)-H bonds in the presence of a chiral Pd/binepine catalyst allows the synthesis of fused cyclopentanes efficiently and in an diastereo- and enantioselective manner (see scheme). © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4480 / 4484

页数：5

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