A Brief History of Fluorescence and Phosphorescence before the Emergence of Quantum Theory

被引:152
|
作者
Valeur, Bernard [1 ,2 ]
Berberan-Santos, Mario N. [3 ,4 ]
机构
[1] Conservatoire Natl Arts & Metiers, F-75003 Paris, France
[2] ENS Cachan, Lab PPSM, Inst Alembert, F-94235 Cachan, France
[3] Inst Super Tecn, Ctr Quim Fis Mol, P-1049001 Lisbon, Portugal
[4] Inst Super Tecn, Inst Nanosci & Nanotechnol, P-1049001 Lisbon, Portugal
关键词
General Public; Upper-Division Undergraduate; Analytical Chemistry; Physical Chemistry; History/Philosophy; Textbooks/Reference Books; Fluorescence Spectroscopy; Quantitative Analysis; UNDERLYING DISTRIBUTIONS; LUMINESCENCE DECAYS; LIGNUM-NEPHRITICUM;
D O I
10.1021/ed100182h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluorescence and phosphorescence are two forms of photoluminescence used in modern research and in practical applications. The early observations of these phenomena, before the emergence of quantum theory, highlight the investigation into the mechanism of light emission. In contrast to incandescence, photoluminescence does not require high temperatures and does not usually produce noticeable heat. Such a "cold light" was the object of an interesting controversy in the 19th century: does it fit into thermodynamics? The early applications, such as the fluorescent tube, fluorescence analysis, and fluorescent tracers, are described.
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页码:731 / 738
页数:8
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