Effect of Pro-degradant Additives Concentration on Aging Properties of Polypropylene Films

被引:19
|
作者
Islam, N. Mohamed [1 ]
Othman, N. [1 ]
Ahmad, Z. [1 ]
Ismail, H. [1 ]
机构
[1] Univ Sains Malaysia, Sch Mat & Mineral Resources Engn, Perai 14300, Pulau Pinang, Malaysia
关键词
Degradable polypropylene; Natural exposure; PP; Pro-degradant additives; Thermo-oxidative aging; LOW-DENSITY POLYETHYLENE; BIODEGRADATION;
D O I
10.1080/03602550903413904
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This paper describes the effect of pro-degradant (PDA) additives on degradation behaviour of polypropylene (PP) films. Thin films (0.12 mm) containing this additives was prepared by sheeting process. The effect of natural exposure (NE) and heating of PP films in the presence or absence of additives were investigated. The apparent density value of PP film contained PDA are proportionate with PDA concentration. Meanwhile melt flow index (MFI) decreased as PDA concentration increased. Changes in tensile properties and carbonyl index (CI) were used to investigate the degradation behavior of the films. The results indicate that the presence of PDA contributes to the degradation and the activity is proportional to the amount of PDA. All samples were found to be more susceptible to thermo-oxidation than to natural exposure.
引用
收藏
页码:272 / 278
页数:7
相关论文
共 50 条
  • [31] Solid-State Drawing of β-Nucleated Polypropylene: Effect of Additives on Drawability and Mechanical Properties
    Luijsterburg, Benny
    Jobse, Peter
    Merino, Daniel Hermida
    Peijs, Ton
    Goossens, Han
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2014, 52 (16) : 1071 - 1082
  • [32] THE EFFECT ON WATER ABSORPTION PROPERTIES OF THE COMPOSITE OF ADDITIVES USED IN POLYPROPYLENE/HAZELNUT SHELL COMPOSITES
    Buyukkaya, Kenan
    Temel, Fulya Aydin
    FRESENIUS ENVIRONMENTAL BULLETIN, 2019, 28 (11A): : 8403 - 8411
  • [33] Effect of beta-phase nucleating additives on structure and properties of blow extruded polypropylene
    Radhakrishnan, S
    Tapale, M
    Shah, N
    Rairkar, E
    Shirodkar, V
    Natu, HP
    JOURNAL OF APPLIED POLYMER SCIENCE, 1997, 64 (07) : 1247 - 1253
  • [34] Effect of aging treatment on the physicochemical properties of collagen films
    Shi, Donghui
    Liu, Fei
    Yu, Zhe
    Chang, Bingyu
    Goff, H. Douglas
    Zhong, Fang
    FOOD HYDROCOLLOIDS, 2019, 87 : 436 - 447
  • [35] Photocuring of Gelatin Films with TMPTMA: Effect on Aging Properties
    Rahman, Nazia
    Khan, Mubarak A.
    Khan, Ruhul A.
    Mollah, M. Z. I.
    Chowdhury, Tofail A.
    MULTI-FUNCTIONAL MATERIALS AND STRUCTURES III, PTS 1 AND 2, 2010, 123-125 : 343 - +
  • [36] Optical properties of highly transparent polypropylene cast films: Influence of material structure, additives, and processing conditions
    Resch, K
    Wallner, GM
    Teichert, C
    Maier, G
    Gahleitner, M
    POLYMER ENGINEERING AND SCIENCE, 2006, 46 (04): : 520 - 531
  • [37] Effect of precursor concentration on the properties of ITO thin films
    Moholkar, A. V.
    Pawar, S. M.
    Rajpure, K. Y.
    Ganesan, V.
    Bhosale, C. H.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 464 (1-2) : 387 - 392
  • [38] Effect of electrolyte concentration on the properties of the electropolymerized polypyrrole films
    Li, YF
    Yang, J
    JOURNAL OF APPLIED POLYMER SCIENCE, 1997, 65 (13) : 2739 - 2744
  • [39] Change of mechanical and electrical properties of polypyrrole films with dopant concentration and oxidative aging
    Kaynak, A
    Rintoul, L
    Graeme, A
    MATERIALS RESEARCH BULLETIN, 2000, 35 (06) : 813 - 824
  • [40] Effect of clay concentration on morphology and properties of hydroxypropylmethylcellulose films
    Mondal, Dibyendu
    Bhowmick, Biplab
    Mollick, Md. Masud R.
    Maity, Dipanwita
    Mukhopadhyay, Asis
    Rana, Dipak
    Chattopadhyay, Dipankar
    CARBOHYDRATE POLYMERS, 2013, 96 (01) : 57 - 63