Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy

被引：34
|
作者：
Wibowo, Rahmat [1 ]
Aldous, Leigh [1 ]
Jacobs, Robert M. J. [2 ]
Manan, Ninie S. A. [3 ,4 ]
Compton, Richard G. [1 ]
机构：
[1] Univ Oxford, Phys & Theoret Chem Lab, Dept Chem, Oxford OX1 3QZ, England
[2] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England
[3] Queens Univ Belfast, QUILL Ctr, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland
[4] Univ Malaya, Fac Sci, Dept Chem, Kuala Lumpur 50603, Malaysia
来源：
CHEMICAL PHYSICS LETTERS | 2011年 / 509卷 / 1-3期
关键词：
SURFACE; XPS; COUPLE; VACUO; MIES; UPS;
D O I：
10.1016/j.cplett.2011.04.071
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C(4)mpyrr][NTf2]), and electrodeposition occurred at a nickel mesh electrode. Potassium electrochemistry was monitored at the ionic liquid-vacuum-electrode interface using a novel cell design. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：72 / 76
页数：5
相关论文
共 50 条
  • [41] Investigation of Surface Oxidation Processes on Manganese Oxide Electrocatalysts Using Electrochemical Methods and Ex Situ X-ray Photoelectron Spectroscopy
    Gorlin, Yelena
    Jaramillo, Thomas F.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (10) : H782 - H786
  • [42] Surface enrichment and depletion effects of ions dissolved in an ionic liquid:: an X-ray photoelectron spectroscopy study
    Maier, Florian
    Gottfried, J. Michael
    Rossa, Jurgen
    Gerhard, Dirk
    Schulz, Peter Steffen
    Schwieger, Wilhelm
    Wasserscheid, Peter
    Steinrueck, Hans-Peter
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (46) : 7778 - 7780
  • [43] Water at the Ionic Liquid-Gas Interface Examined by Ambient Pressure X-ray Photoelectron Spectroscopy
    Broderick, Alicia
    Khalifa, Yehia
    Shiflett, Mark B.
    Newberg, John T.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (13): : 7337 - 7343
  • [44] Interactions between Lithium, an Ionic Liquid, and Si(111) Surfaces Studied by X-ray Photoelectron Spectroscopy
    Liu, Zhen
    Li, Guozhu
    Borodin, Andriy
    Liu, Xiaoxu
    Li, Yao
    Endres, Frank
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (16): : 4673 - 4678
  • [45] Surface studies on the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate using X-ray photoelectron spectroscopy (XPS)
    Gottfried, J. M.
    Maier, F.
    Rossa, J.
    Gerhard, D.
    Schulz, P. S.
    Wasserscheid, P.
    Steinrueck, H. -P.
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2006, 220 (10-11): : 1439 - 1453
  • [46] Monitoring DNA hybridization by quantification of nitrogen content using X-ray photoelectron spectroscopy
    Lapicki, Adam
    Sakamoto, Fumitaka
    Sandhu, Adarsh
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2007, 46 (1-3): : L49 - L52
  • [47] Investigation of the Electrode/Ionic Liquid Interphase: Chemical Reactions of an Ionic Liquid and a Lithium Salt with Lithiated Graphite Probed by X-ray Photoelectron Spectroscopy
    Liu, Zhen
    Li, Guozhu
    Borodin, Andriy
    Liu, Xiaoxu
    Li, Yao
    Endres, Frank
    JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (16): : 10325 - 10332
  • [48] Study of the potassium bromide surface after laser effects using x-ray photoelectron spectroscopy
    Savintsev, A. P.
    Gavasheli, Yu O.
    Kalazhokov, Z. Kh
    Kalazhokov, Kh Kh
    XXXIII INTERNATIONAL CONFERENCE ON EQUATIONS OF STATE FOR MATTER, 2019, 1147
  • [49] Probing the electronic structure of ether functionalised ionic liquids using X-ray photoelectron spectroscopy
    Dick, Ejike J.
    Fouda, Adam E. A.
    Besley, Nicholas A.
    Licence, Peter
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (03) : 1624 - 1631
  • [50] Surface Analysis of Ionic Liquids with and without Lithium Salt Using X-ray Photoelectron Spectroscopy
    Kurisaki, Tsutomu
    Tanaka, Daisaku
    Inoue, Yoshiki
    Wakita, Hisanobu
    Minofar, Babak
    Fukuda, Shuhei
    Ishiguro, Shin-ichi
    Umebayashi, Yasuhiro
    JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 116 (35): : 10870 - 10875
12345