Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy

被引：34

作者：

Wibowo, Rahmat ^{[1
]}

Aldous, Leigh ^{[1
]}

Jacobs, Robert M. J. ^{[2
]}

Manan, Ninie S. A. ^{[3
,4
]}

Compton, Richard G. ^{[1
]}

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Dept Chem, Oxford OX1 3QZ, England

[2] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England

[3] Queens Univ Belfast, QUILL Ctr, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

[4] Univ Malaya, Fac Sci, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

CHEMICAL PHYSICS LETTERS | 2011年 / 509卷 / 1-3期

关键词：

SURFACE; XPS; COUPLE; VACUO; MIES; UPS;

D O I：

10.1016/j.cplett.2011.04.071

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C(4)mpyrr][NTf2]), and electrodeposition occurred at a nickel mesh electrode. Potassium electrochemistry was monitored at the ionic liquid-vacuum-electrode interface using a novel cell design. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：72 / 76

页数：5

共 50 条

[1] In situ electrochemical-X-ray Photoelectron Spectroscopy: Rubidium metal deposition from an ionic liquid in competition with solvent breakdown
Wibowo, Rahmat
Aldous, Leigh
Jacobs, Robert M. J.
Manan, Ninie S. A.
Compton, Richard G.
CHEMICAL PHYSICS LETTERS, 2011, 517 (1-3) : 103 - 107
[2] Electrowetting of Ionic Liquid on Graphite: Probing via in Situ Electrochemical X-ray Photoelectron Spectroscopy
Panhwar, Ghulam M.
Mysyk, Roman
Rojo, Teofilo
Shaikhutdinov, Shamil
Bondarchuk, Oleksandr
LANGMUIR, 2018, 34 (48) : 14528 - 14536
[3] Core Level Data of Ionic Liquids: Monitoring Charging by In Situ Electrochemical X-ray Photoelectron Spectroscopy
Foelske-Schmitz, Annette
Weingarth, Daniel
Wokaun, Alexander
Koetz, Ruediger
ECS ELECTROCHEMISTRY LETTERS, 2013, 2 (04) : H13 - H15
[4] Potential Screening at Electrode/Ionic Liquid Interfaces from In Situ X-ray Photoelectron Spectroscopy
Greco, Francesco
Shin, Sunghwan
Williams, Federico J.
Heller, Bettina S. J.
Maier, Florian
Steinrueck, Hans-Peter
CHEMISTRYOPEN, 2019, 8 (12) : 1365 - 1368
[5] Electrodeposition of Indium from an Ionic Liquid Investigated by In Situ Electrochemical XPS
Liu, Zhen
Cheng, Jun
Hoefft, Oliver
Endres, Frank
METALS, 2022, 12 (01)
[6] X-ray Photoelectron Spectroscopy and in Situ X-ray Absorption Spectroscopy Studies on Reversible Insertion/Desertion of Dicyanamide Anions into/from Manganese Oxide in Ionic Liquid
Chang, Jeng-Kuei
Lee, Ming-Tsung
Tsai, Wen-Ta
Deng, Ming-Jay
Sun, I-Wen
CHEMISTRY OF MATERIALS, 2009, 21 (13) : 2688 - 2695
[7] In situ x-ray photoelectron spectroscopy for electrochemical reactions in ordinary solvents
Masuda, Takuya
Yoshikawa, Hideki
Noguchi, Hidenori
Kawasaki, Tadahiro
Kobata, Masaaki
Kobayashi, Keisuke
Uosaki, Kohei
APPLIED PHYSICS LETTERS, 2013, 103 (11)
[8] In situ x-ray photoelectron spectroscopy for thin film synthesis monitoring
Kelly, MA
Shek, ML
Pianetta, P
Gür, TM
Beasley, MR
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 2001, 19 (05): : 2127 - 2133
[9] Observing the Electrochemical Oxidation of Co Metal at the Solid/Liquid Interface Using Ambient Pressure X-ray Photoelectron Spectroscopy
Han, Yong
Axnanda, Stephanus
Crumlin, Ethan J.
Chang, Rui
Mao, Baohua
Hussain, Zahid
Ross, Philip N.
Li, Yimin
Liu, Zhi
JOURNAL OF PHYSICAL CHEMISTRY B, 2018, 122 (02): : 666 - 671
[10] Probing the solid/gas and solid/liquid electrochemical interfaces using in situ/operando ambient pressure X-ray photoelectron spectroscopy
Crumlin, Ethan
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250

← 1 2 3 4 5 →