Vinyl imidates in cycloaddition reactions:: A formal synthesis of (±)-reserpine

被引：10
|
作者：
Sparks, SM [1 ]
Shea, KJ [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 15期
关键词：
D O I：
10.1021/ol015988w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The intramolecular Diets-Alder reaction of N-acylvinylimidates provides an efficient entry into cis-fused perhydroisoquinoline ring systems. This is demonstrated by the preparation of isoquinoline 2, an intermediate, which has been previously transformed to reserpine.
引用
收藏
页码：2265 / 2267
页数：3
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