Ethanol catalyzed synthesis of titanocene aryl carboxylate complexes and crystal structure of (η5-C5H5)2Ti(2-OH-5-S-O2CC6H3)2

被引：3
|
作者：
Li, Jin-Ling [1 ,2 ,3 ]
Gao, Zi-Wei [1 ,2 ,3 ]
Sun, Ping [1 ,2 ,3 ]
Gao, Ling-Xiang [1 ,2 ,3 ]
Tikkanen, Wayne [4 ]
机构：
[1] Shaanxi Normal Univ, Key Lab Appl Surface & Colloid Chem, Minist Educ, Xian 710062, Peoples R China
[2] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[4] Calif State Univ Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90032 USA
来源：
INORGANICA CHIMICA ACTA | 2011年 / 368卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Ethanol; Sodium hydroxide; Catalytic reaction; Titanocene complex; ORGANOMETALLIC ANTICANCER AGENTS; DICHLORIDE DERIVATIVES; POLYMERIZATION; CYTOTOXICITY; ZIRCONOCENE; COORDINATION; TITANIUM(IV); NUCLEOTIDES; SALICYLATE; CHEMISTRY;
D O I：
10.1016/j.ica.2010.12.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A method for the synthesis of titanocene (IV) aryl carboxylate complexes is presented in this paper. It is based on the fact that alcohol can catalyze the reaction between Cp2TiCl2 and aryl carboxylate ligands in the presence of sodium hydroxide (NaOH). The effects of the catalyst on the reaction system were studied and the possible reaction mechanism was proposed. This method was used to prepare a series of titanocene (IV) aryl carboxylate complexes and a macrocyclic titanocene (5,5'-dithiodisalicylato titanocene), whose structure was determined by X-ray diffraction analysis. (C) 2010 Elsevier B.V. All rights reserved.
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页码：231 / 236
页数：6
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