Ethanol catalyzed synthesis of titanocene aryl carboxylate complexes and crystal structure of (η5-C5H5)2Ti(2-OH-5-S-O2CC6H3)2

被引：3

作者：

Li, Jin-Ling ^{[1
,2
,3
]}

Gao, Zi-Wei ^{[1
,2
,3
]}

Sun, Ping ^{[1
,2
,3
]}

Gao, Ling-Xiang ^{[1
,2
,3
]}

Tikkanen, Wayne ^{[4
]}

机构：

[1] Shaanxi Normal Univ, Key Lab Appl Surface & Colloid Chem, Minist Educ, Xian 710062, Peoples R China

[2] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China

[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[4] Calif State Univ Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90032 USA

来源：

INORGANICA CHIMICA ACTA | 2011年 / 368卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Ethanol; Sodium hydroxide; Catalytic reaction; Titanocene complex; ORGANOMETALLIC ANTICANCER AGENTS; DICHLORIDE DERIVATIVES; POLYMERIZATION; CYTOTOXICITY; ZIRCONOCENE; COORDINATION; TITANIUM(IV); NUCLEOTIDES; SALICYLATE; CHEMISTRY;

D O I：

10.1016/j.ica.2010.12.037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A method for the synthesis of titanocene (IV) aryl carboxylate complexes is presented in this paper. It is based on the fact that alcohol can catalyze the reaction between Cp2TiCl2 and aryl carboxylate ligands in the presence of sodium hydroxide (NaOH). The effects of the catalyst on the reaction system were studied and the possible reaction mechanism was proposed. This method was used to prepare a series of titanocene (IV) aryl carboxylate complexes and a macrocyclic titanocene (5,5'-dithiodisalicylato titanocene), whose structure was determined by X-ray diffraction analysis. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：231 / 236

页数：6

共 50 条

[1] Synthesis and crystal structure of (η5-C5H5)2Ti(NH(2,4-(CCSiMe3)2C6H3))2
Zhang, LL
Waheed, A
Jones, RA
Lynch, VM
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2005, 35 (09) : 673 - 677
[2] CRYSTAL AND MOLECULAR-STRUCTURE OF TITANOCENE DICARBONYL, (H5-C5H5)2TI(CO)2
ATWOOD, JL
STONE, KE
ALT, HG
HRNCIR, DC
RAUSCH, MD
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 96 (01) : C4 - C6
[3] CRYSTAL AND MOLECULAR STRUCTURE OF (C5H5)2TI(C6H5)2
KOCMAN, V
RUCKLIDG.JC
OBRIEN, RJ
SANTO, W
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (21): : 1340 - &
[4] SYNTHESIS AND CRYSTAL STRUCTURE OF （C5H5）2Ti（o-NHPhC6H4CO2）2
Wang Zhi-Qiang Lu Shi-Wei Guo He-FuDalian Institute of Chemical Physics
结构化学, 1992, (02) : 130 - 133
[5] SYNTHESIS AND SOME REACTIONS OF (C5H5)2TI[GE(C6H5)3]2
RAZUVAEV, GA
LATYAEVA, VN
VASILEVA, GA
VYSHINSK.LI
IZVESTIYA AKADEMII NAUK SSSR-SERIYA KHIMICHESKAYA, 1972, (07): : 1658 - +
[6] Synthesis and Anti-inflammatory Action of (η-C5H5)2Ti(Sal)2 and (η-C5H5)2Ti(Clo)2
LI Xiu-juan and ZENG Zheng-zhi ** College of Chemistry and Chemical Engineering
ChemicalResearchinChineseUniversities, 2006, (01) : 6 - 10
[7] Synthesis of the (σ-1,3-butadiyn-1-yl)titanocenes (η5-C5H4SiMe3)2Ti(C=CC=CC2-H5 )(CI) and (η5-C5H4SiMe3)2Ti(C=CC=C-C2H5 )2 and their reactions with copper(I) halices
Lang, H.
Weber, C.
Organometallics, 1995, 14 (09)
[8] CRYSTAL STRUCTURE OF FeaTe2（CO）6（NO）(η5-C5H5)
Yang Xiaoguang Huang Jinshun and Huang JinlingFujian Institute of Research on the Structure of Matter
结构化学, 1985, (02) : 136 - 138
[9] CATIONIC COMPLEXES WITH (ETA-5-C5H5)2TIIV COMPONENT GROUPS - SYNTHESIS AND STRUCTURE OF "[(ETA-5-C5H5)2TI(BIPY)]2+(CF3SO3-)2 AND "[(ETA-5-C5H5)2TI(PHEN)]2+(CF3SO3-)2
THEWALT, U
BERHALTER, K
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 302 (02) : 193 - 200
[10] Synthesis and Crystal Structure of[（2 , 4-Me2C5H5）2NdC ＝CC6H5]2
ZHANG Suo-bo and LIU Ju-zheng(Department of Chemistry
JIA Heng-qing and CHEN Wen-qi(Changchun Institute of Applied Chemistry
ChemicalResearchinChineseUniversities, 1994, (04) : 308 - 312

← 1 2 3 4 5 →