Novel heterogeneous catalyst, supported undecamolybdophosphate: synthesis, physico-chemical characterization and solvent-free oxidation of styrene

被引：41
|
作者：
Pathan, Soyeb [1 ]
Patel, Anjali [1 ]
机构：
[1] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Vadodara 390002, India
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 02期
关键词：
SOLID ACID CATALYST; SELECTIVE OXIDATION; EPOXIDATION; EFFICIENT; OLEFINS; PHENOL; NMR;
D O I：
10.1039/c0dt01187h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel heterogeneous catalyst comprising undecamolybdophosphate and hydrous zirconia was synthesized, characterized by various physicochemical techniques and used as an efficient heterogeneous catalyst for oxidation of styrene using H2O2 as an oxidant. The novelty of the present work lies in obtaining >99% conversion of styrene with >99% selectivity for benzaldehyde under solvent free mild reaction conditions.
引用
收藏
页码：348 / 355
页数：8
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