Stable intramolecularly base-stabilized germylene- and stannylene-borane adducts:: M[C6H3(NMe2)2-2,6]2BH3 (M = Ge, Sn)

被引：52
|
作者：
Drost, C [1 ]
Hitchcock, PB [1 ]
Lappert, MF [1 ]
机构：
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Chem Lab, Brighton BN1 9QJ, E Sussex, England
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 18期
关键词：
D O I：
10.1021/om980388v
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of two novel and thermally surprisingly stable main-group-element Lewis acid (BH3) adducts (3 and 4) of a monomeric germylene (1) and of a diarylstannylene (2) is reported. X-ray crystal structures of the adducts MAr2(BH3) reveal a four-coordinated germanium (3) but five-coordinated tin (4), with regard to the C,N-potentially bidentate chelating ligand -C6H3(NMe2)(2)-1,2 and BH3, respectively.
引用
收藏
页码：3838 / 3840
页数：3
相关论文
共 50 条
  • [21] TUNING OF TANTALUM ALKYLIDENE REACTIVITY WITH A TERDENTATE ARYL AMINE LIGAND - SYNTHESIS, STRUCTURE AND REACTIVITY OF [TACL2(C6H3(CH2NME2)2-2,6)(CHBU-TERT)]
    ABBENHUIS, HCL
    GROVE, DM
    VANDERSLUIS, P
    SPEK, AL
    VANKOTEN, G
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1990, 109 (7-8): : 446 - 448
  • [22] Versatile N,C,N coordination behavior of a monoanionic aryldiamine ligand in ruthenium(II) complexes: Syntheses and crystal structures of [Ru-II(C6H3(CH(2)NMe(2))(2)-2,6)X(L)] (L equals norbornadiene, X=Cl, SO3CF3; L=PPh(3), X=I) and [Ru-II{C6H3(CH(2)NMe(2))(2)-2,6}(2,2':6:2''-terpyridine)]Cl
    Sutter, JP
    James, SL
    Steenwinkel, P
    Karlen, T
    Grove, DM
    Veldman, N
    Smeets, WJJ
    Spek, AL
    vanKoten, G
    ORGANOMETALLICS, 1996, 15 (03) : 941 - 948
  • [23] Preparation and electrochemical behaviour of dinuclear platinum complexes containing NCN ligands (NCN = [C6H3(Me2NCH2)2-2,6]-).: The crystal structure of [C6H3(Me2NCH2)2-1,3-(CC)-5]2
    Back, S
    Lutz, M
    Spek, AL
    Lang, H
    van Koten, G
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 620 (1-2) : 227 - 234
  • [24] Unusual reactivity of a sterically hindered diphosphazane ligand, EtN{P(OR)2}2, (R = C6H3(Pri)2-2,6) towards (η3-allyl)palladium precursors
    Krishna, Heera
    Krishnamurthy, Setharampattu S.
    Nethaji, Munirathinam
    Murugavel, Ramaswamy
    Prabusankar, Ganesan
    DALTON TRANSACTIONS, 2007, (27) : 2908 - 2914
  • [25] A solid state study of the configuration and conformation of O=S=N-R (R = C6H5 and C6H3(CH3-CH2)2-2,6)
    Romano, RM
    Della Védova, CO
    Boese, R
    JOURNAL OF MOLECULAR STRUCTURE, 1999, 475 (01) : 1 - 4
  • [26] Mono- and dianionic guanidinate ligands.: Reactivity of [iPrN=C(NiPr)2]Ta(NMe2)3 and [(iPrNH)C (NiPr)2]TaCl(NMe2)3 with Me3SiCl and ArNC (Ar=2,6-Me2C6H4)
    Thirupathi, N
    Yap, GPA
    Richeson, DS
    ORGANOMETALLICS, 2000, 19 (13) : 2573 - 2579
  • [27] Thermally stable heterobinuclear bivalent group 14 metal complexes Ar2M-Sn[1,8-(NR)2C10H6] (M = Ge, Sn; Ar = 2,6-(Me2N)2C6H3, R = Ch2tBu)
    Drost, C
    Hitchcock, PB
    Lappert, MF
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1999, 38 (08) : 1113 - 1116
  • [28] FLUXIONALITY AND BONDING IN FORMAMIDINE AND FORMAMIDINATE COMPLEXES OF PT-II AND PD-II CONTAINING THE 2,6-BIS[(DIMETHYLAMINO)METHYL]PHENYL LIGAND - A PROTON NUCLEAR-MAGNETIC-RESONANCE STUDY WITH X-RAY CRYSTAL-STRUCTURES OF [PT(C6H3(CH2NME2)2-2,6)(PARA-MEC6H4N=CHN(H)C6H4ME-P)][CF3SO3] AND [PT(C6H3(CH2NME2)2-2,6)(PARA-MEC6H4N=CHNC6H4ME-P)]N
    GROVE, DM
    VANKOTEN, G
    UBBELS, HJC
    VRIEZE, K
    NIEMANN, LC
    STAM, CH
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (04): : 717 - 724
  • [29] NOVEL 5-CO-ORDINATE DIORGANORHODIUM COMPOUNDS - X-RAY STRUCTURE OF BIS-ORTHO-CHELATED [RHIII(ME)L(C6H3(CH2NME2)2-2,6)]
    VANDERZEIJDEN, AAH
    VANKOTEN, G
    ERNSTING, JM
    ELSEVIER, CJ
    KRIJNEN, B
    STAM, CH
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (02): : 317 - 324
  • [30] SYNTHESIS AND REACTIVITY TOWARDS DIIODINE OF PALLADIUM(II) AND PLATINUM(II) COMPLEXES WITH NONCYCLIC AND CYCLIC LIGANDS (C6H3(CH2NR1R2)2-2,6)- - END-ON DIIODINE-PLATINUM(II) BONDING IN MACROCYCLIC [PTI(C6H3(CH2NME(CH2)7MENCH2)-2,6)(ETA-1-I2)]
    VANBEEK, JAM
    VANKOTEN, G
    DEKKER, GPCM
    WISSING, E
    ZOUTBERG, MC
    STAM, CH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 394 (1-3) : 659 - 678
12345