Photochromic Terbium Phosphonates with Photomodulated Luminescence and Metal Ion Sensitive Detection

被引：67
|
作者：
Yang, Weiting [1 ]
Tian, Hong-Rui [1 ]
Li, Jian-Ping [1 ]
Hui, Yuan-Feng [1 ]
He, Xiang [2 ]
Li, Jiyang [3 ]
Dang, Song [1 ]
Xie, Zhigang [4 ]
Sun, Zhong-Ming [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China
[2] Shanghai Univ, Innovat Drug Res Ctr, Dept Chem, Shanghai 200444, Peoples R China
[3] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[4] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 43期
基金：
中国国家自然科学基金;
关键词：
lanthanide phosphonate; luminescence; multiphotofunctionality; photochromism; sensors; BASIC PYRIDYL SITES; ORGANIC FRAMEWORK; METHYL VIOLOGEN; ELECTRON-TRANSFER; SMALL MOLECULES; LANTHANIDE PHOSPHONATES; ROOM-TEMPERATURE; COORDINATION; COMPLEXES; CHEMISTRY;
D O I：
10.1002/chem.201602779
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rational selection and modification of rare earth metal centers and photoactive organic linkers enables designable multiphotofunctionality to come to fruition in new hybrid coordination polymer materials. By using a viologen-functionalized diphosphonate linker, two terbium phosphonate compounds (Tb-1 and Tb-2) have been constructed, which display reversible photochromic reactions in response to UV light and soft X-ray irradiation. In addition, the photo-induced electron-transfer reaction can modulate the luminescent emission to thus realize photoluminescence switching behavior. Furthermore, both terbium phosphonates can serve as highly sensitive sensors to probe Cu2+ in solution through their luminescence. Thus, they represent the first photochromic examples of lanthanide phosphonate-based materials with photomodulated luminescence and sensitive detection of metal ions.
引用
收藏
页码：15451 / 15457
页数：7
相关论文
共 50 条
  • [41] A novel photochromic metal organic framework based on viologen exhibiting benzene detection and photocontrolled luminescence properties in solid state
    Cui, Shuxin
    Zou, Yongcun
    Yu, Jinhuan
    Yin, Qianzhu
    Zhang, Wenwen
    Xing, Lehong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2019, 110
  • [42] Excimer Formation in a Terbium Metal-Organic Framework Assists Luminescence Thermometry
    Ananias, Duarte
    Firmino, Ana D. G.
    Mendes, Ricardo F.
    Almeida Paz, Filipe A.
    Nolasco, Mariela
    Carlos, Luis D.
    Rocha, Joao
    CHEMISTRY OF MATERIALS, 2017, 29 (21) : 9547 - 9554
  • [43] Highly sensitive Fe3+ luminescence detection via single-ion adsorption
    Yujing Li
    Xiaojun Zhang
    Zicheng Wang
    Lina Zhao
    Yuxin Li
    ChineseChemicalLetters, 2024, 35 (01) : 457 - 460
  • [44] Highly sensitive Fe 3+luminescence detection via single-ion adsorption
    Li, Yujing
    Zhang, Xiaojun
    Wang, Zicheng
    Zhao, Lina
    Li, Yuxin
    CHINESE CHEMICAL LETTERS, 2024, 35 (01)
  • [45] Luminescence detection of cysteine based on Ag+-mediated conformational change of terbium ion-promoted G-quadruplex
    Tan, Hongliang
    Tang, Gonge
    Ma, Chanjiao
    Li, Qian
    ANALYTICA CHIMICA ACTA, 2016, 908 : 161 - 167
  • [46] A sensitive aptasensor based on rolling circle amplification and G-rich ssDNA/terbium (III) luminescence enhancement for ofloxacin detection in food
    Huang, Yukun
    Wang, Chong
    Wei, Qiming
    Song, Yaning
    Chen, Pengfei
    Wang, Lijun
    Yang, Xiao
    Chen, Xianggui
    TALANTA, 2021, 235
  • [47] Nanostructured and Photochromic Material for Environmental Detection of Metal Ions
    Machado, Raphael C. L.
    Alexis, Frank
    De Sousa, Frederico B.
    MOLECULES, 2019, 24 (23):
  • [48] High-Sensitive Hydrogel Optofluidic Microcavities for Heavy Metal Ion Detection
    Wu, Ruijie
    Wang, Ziyihui
    Fu, Yaoxin
    Jiang, Junfeng
    Chen, Yu-Cheng
    Liu, Tiegen
    ACS SENSORS, 2025, : 2330 - 2338
  • [49] Thermodynamic and kinetic analysis of metal ion complexation by photochromic spiropyrans
    M. I. Zakharova
    V. Pimienta
    A. V. Metelitsa
    V. I. Minkin
    J. C. Micheaua
    Russian Chemical Bulletin, 2009, 58 : 1329 - 1337
  • [50] Thermodynamic and kinetic analysis of metal ion complexation by photochromic spiropyrans
    Zakharova, M. I.
    Pimienta, V.
    Metelitsa, A. V.
    Minkin, V. I.
    Micheaua, J. C.
    RUSSIAN CHEMICAL BULLETIN, 2009, 58 (07) : 1329 - 1337
12345