Photochromic Terbium Phosphonates with Photomodulated Luminescence and Metal Ion Sensitive Detection

被引：67
|
作者：
Yang, Weiting [1 ]
Tian, Hong-Rui [1 ]
Li, Jian-Ping [1 ]
Hui, Yuan-Feng [1 ]
He, Xiang [2 ]
Li, Jiyang [3 ]
Dang, Song [1 ]
Xie, Zhigang [4 ]
Sun, Zhong-Ming [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China
[2] Shanghai Univ, Innovat Drug Res Ctr, Dept Chem, Shanghai 200444, Peoples R China
[3] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[4] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 43期
基金：
中国国家自然科学基金;
关键词：
lanthanide phosphonate; luminescence; multiphotofunctionality; photochromism; sensors; BASIC PYRIDYL SITES; ORGANIC FRAMEWORK; METHYL VIOLOGEN; ELECTRON-TRANSFER; SMALL MOLECULES; LANTHANIDE PHOSPHONATES; ROOM-TEMPERATURE; COORDINATION; COMPLEXES; CHEMISTRY;
D O I：
10.1002/chem.201602779
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rational selection and modification of rare earth metal centers and photoactive organic linkers enables designable multiphotofunctionality to come to fruition in new hybrid coordination polymer materials. By using a viologen-functionalized diphosphonate linker, two terbium phosphonate compounds (Tb-1 and Tb-2) have been constructed, which display reversible photochromic reactions in response to UV light and soft X-ray irradiation. In addition, the photo-induced electron-transfer reaction can modulate the luminescent emission to thus realize photoluminescence switching behavior. Furthermore, both terbium phosphonates can serve as highly sensitive sensors to probe Cu2+ in solution through their luminescence. Thus, they represent the first photochromic examples of lanthanide phosphonate-based materials with photomodulated luminescence and sensitive detection of metal ions.
引用
收藏
页码：15451 / 15457
页数：7
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