Nickel(II)-catalyzed direct arylation of aryl C-H bonds with aryl-boron reagents directed by a removable bidentate auxiliary

被引：29
|
作者：
Liu, Bin [1 ]
Zhang, Zhuo-Zhuo [1 ]
Li, Xin [1 ]
Shi, Bing-Feng [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2016年 / 3卷 / 07期
关键词：
UNACTIVATED C(SP(3))-H BONDS; CATALYZED DIRECT THIOLATION; CARBON-HYDROGEN BONDS; ALIPHATIC AMIDES; C(SP(2))-H BONDS; CHELATION ASSISTANCE; AROMATIC KETONES; ACTIVATION; FUNCTIONALIZATION; ALKYLATION;
D O I：
10.1039/c6qo00149a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ni(II)-catalyzed C-H arylation using Ar2I+X- or ArX as the arylating reagent via oxidative addition has been well investigated. However, the analogous cross-coupling of C-H bonds with organoboron reagents via transmetallation remains a great challenge. Here we report the first Ni(II)-catalyzed direct C-H arylation with arylboronic acid esters assisted by a removable bidentate auxiliary. This procedure is scalable and compatible with a wide range of functional groups, providing a complementary protocol for the synthesis of biaryl compounds.
引用
收藏
页码：897 / 900
页数：4
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