Construction of Multifunctional 3-Amino-2-carbamimidoylacrylamides and Their Crystalline Channel-Type Inclusion Complexes

被引：10

作者：

Wang, Jinjin ^{[1
]}

Liu, Jiyong ^{[1
]}

Ding, Hualong ^{[1
]}

Wang, Jing ^{[1
]}

Lu, Ping ^{[1
]}

Wang, Yanguang ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 11期

关键词：

SOLID-STATE; TERMINAL ALKYNES; AZIDES; CYCLODEXTRIN; ACID; KETENIMINES; MOLECULES; CHEMISTRY; TAUTOMERS; SULFONYL;

D O I：

10.1021/acs.joc.5b00827

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-Amino-2-carbarmimidoylacrylamides were efficiently prepared via a copper(I)-catalyzed three-component reaction of sulfonylaides, propriolamides, and amidines. The synthesized compounds provided three kinds of crystalline structures based on the position of halogen. Two of them presented channel-type inclusion complexes with ethyl acetate through intermolecular hydrogen bonding, intermolecular C-H center dot center dot center dot pi and pi-pi interactions, and van der Waals forces.

引用

页码：5842 / 5850

页数：9

共 32 条

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