Synthesis, characterisation and dissociation of a glycinate bridged trinuclear Co(III)-Cu(II)-Co(III) complex

被引：0

作者：

Das, NN ^{[1
]}

Dash, A

Brahama, GS

Mohanty, P

机构：

[1] Natl Met Lab, Div Analyt Chem, Jamshedpur 831007, Bihar, India

[2] Utkal Univ, Dept Chem, Bhubaneswar 751004, Orissa, India

来源：

INORGANIC REACTION MECHANISMS | 2003年 / 5卷 / 01期

关键词：

cobalt(III); copper(II); glycinate; trinuclear complex; dissociation kinetics;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A trinuclear complex, [{(NH3)(5)Co(O2CCH2NH))(2)Cu](ClO4)(6).2H(2)O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.

引用

页码：73 / 77

页数：5

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