Synthesis, characterisation and dissociation of a glycinate bridged trinuclear Co(III)-Cu(II)-Co(III) complex

被引：0
|
作者：
Das, NN [1 ]
Dash, A
Brahama, GS
Mohanty, P
机构：
[1] Natl Met Lab, Div Analyt Chem, Jamshedpur 831007, Bihar, India
[2] Utkal Univ, Dept Chem, Bhubaneswar 751004, Orissa, India
来源：
INORGANIC REACTION MECHANISMS | 2003年 / 5卷 / 01期
关键词：
cobalt(III); copper(II); glycinate; trinuclear complex; dissociation kinetics;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A trinuclear complex, [{(NH3)(5)Co(O2CCH2NH))(2)Cu](ClO4)(6).2H(2)O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.
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页码：73 / 77
页数：5
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