A novel luminescent copper(I) complex containing an acetylenediide-bridged, butterfly-shaped tetranuclear core

被引:38
|
作者
Song, HB
Wang, QM
Zhang, ZZ
Mak, TCW [1 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
关键词
D O I
10.1039/b102717b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel luminescent acetylenediide-bridged tetranuclear copper(I) complex [Cu-4(mu -Ph2Ppypz)(4)(mu (4)-eta (1),eta (2)-C=C)]-(ClO4)(2) [Ph(2)Ppypz = 2-(diphenylphosphino-6-pyrazol-1-yl)pyridine] has been synthesized and structurally characterized by X-ray crystallography.
引用
收藏
页码:1658 / 1659
页数:2
相关论文
共 50 条
  • [41] A new tetranuclear copper(II) complex containing decameric water clusters bridged by-OH-and pyridine-2,4, 6-tricarboxylate: synthesis and magnetic characterization
    Wang, Liya
    Wang, Jiange
    Xie, Chengzhi
    JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (21) : 3401 - 3409
  • [42] A novel triply bridged dinuclear four-coordinate copper(I) complex with sterically bulky bis(dicyclohexylphosphino)methane ligand
    Yao, Zu-Fu
    Gan, Xin
    Fu, Wen-Fu
    CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2008, 6 (04): : 613 - 616
  • [43] Diamond-shaped heterometallic complexes of Iron(II) and copper(I) bridged by cyanide groups containing monodentate or bidentate phosphanes bound to copper(I), including an alternative structure based on the nature of the bidentate phosphane ligand
    Darensbourg, DJ
    Lee, WZ
    Adams, MJ
    Yarbrough, JC
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (11) : 2811 - 2822
  • [44] A Dodecanuclear Copper(I) Complex Containing a Cubic (CuS)4 Core Stabilized by a Tripodal (N,N,P)-Chelating Ligand
    Meinholz, Margret M.
    Stalke, Dietmar
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2011, 66 (10): : 981 - 984
  • [45] An extremely rare example of asymmetric tetranuclear core {M4(μ3-X)2(μ-X)4} in a novel alkoxo-bridged heterometallic Cr/Cd complex
    Semenaka, Valentyna V.
    Nesterova, Oksana V.
    Kokozay, Volodymyr N.
    Dyakonenko, Viktoriya V.
    Shishkin, Oleg V.
    Boca, Roman
    Jezierska, Julia
    DALTON TRANSACTIONS, 2010, 39 (07) : 1734 - 1739
  • [46] Chiral tetranuclear μ3-alkoxo-bridged Copper(II) complex with 2+4 cubane-like Cu4O4 core framework and ferromagnetic ground state
    Burkhardt, Anja
    Spielberg, Eike T.
    Goerls, Helmar
    Plass, Winfried
    INORGANIC CHEMISTRY, 2008, 47 (07) : 2485 - 2493
  • [47] Microwave-assisted synthesis, crystal structures and DFT calculations of two novel silver(I) dimers [Ag2(μ-X)2(μ-dppm)(PPh3)2] (X = Br, I) with butterfly-shaped dinuclear cores
    Luo, Geng-Geng
    Wu, Rui-Bo
    Sun, Di
    Chen, Jian-Hua
    Zhang, Na
    Huang, Rong-Bin
    Lin, Li-Rong
    Zheng, Lan-Sun
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 930 (1-3) : 9 - 14
  • [48] A novel tetra(μ3-phenoxo) bridged copper(II) Schiff base complex containing a Cu4O4 cubane core: Synthesis, structural aspects and magneto-structural correlations
    Chakraborty, Joy
    Thakurta, Santarupa
    Pilet, Guillaume
    Luneau, Dominique
    Mitra, Samiran
    POLYHEDRON, 2009, 28 (04) : 819 - 825
  • [49] Synthesis, crystal structure and luminescent properties of a dinuclear copper(I) complex containing 2, 9-di-n-butyl-1, 10-phenanthroline
    Liu, Wen-Song
    Ren, Hong-Yang
    Li, Xiang-Qi
    Wang, Bing-Xi
    Faguang Xuebao/Chinese Journal of Luminescence, 2012, 33 (12): : 1277 - 1282
  • [50] Novel tetranuclear Ni(II) Schiff base complex containing Ni4O4 cubane core: Synthesis, X-ray structure, spectra and magnetic properties
    Jana, Mahendra Sekhar
    Priego, Jose L.
    Jimenez-Aparicio, Reyes
    Mondal, Tapan Kumar
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 133 : 714 - 719