Ammonia synthesis at atmospheric pressure

被引:483
|
作者
Marnellos, G [1 ]
Stoukides, M
机构
[1] Aristotelian Univ Salonika, Dept Chem Engn, GR-54006 Salonika, Greece
[2] Aristotelian Univ Salonika, Chem Proc Engn Res Inst, GR-54006 Salonika, Greece
关键词
D O I
10.1126/science.282.5386.98
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Ammonia was synthesized from its elements at atmospheric pressure in a solid state proton (H+)-conducting cell-reactor. Hydrogen was flowing over the anode and was converted into protons that were transported through the solid electrolyte and reached the cathode (palladium) over which nitrogen was passing. At 570 degrees C and atmospheric pressure, greater than 78 percent of the electrochemically supplied hydrogen was converted into ammonia. The thermodynamic requirement for a high-pressure process is eliminated.
引用
收藏
页码:98 / 100
页数:3
相关论文
共 50 条
  • [31] Electrolytic ammonia synthesis from water and nitrogen gas in molten salt under atmospheric pressure
    Murakami, T
    Nohira, T
    Goto, T
    Ogata, YH
    Ito, Y
    ELECTROCHIMICA ACTA, 2005, 50 (27) : 5423 - 5426
  • [32] Chromium as reactant for solar thermochemical synthesis of ammonia from steam, nitrogen, and biomass at atmospheric pressure
    Michalsky, Ronald
    Pfromm, Peter H.
    SOLAR ENERGY, 2011, 85 (11) : 2642 - 2654
  • [33] MAGNETOCATALYTIC EFFECT IN AMMONIA SYNTHESIS AT ATMOSPHERIC PRESSURES
    IVANOV, DG
    VISOKOV, GP
    ZHURNAL PRIKLADNOI KHIMII, 1972, 45 (02) : 252 - &
  • [34] Measurement of the solubility of ammonia and nitrogen in gallium at atmospheric pressure
    Garcia, R.
    Ren, B.
    Thomas, A. C.
    Ponce, F. A.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 467 (1-2) : 611 - 613
  • [35] Synthesis of todorokite at atmospheric pressure
    Feng, XH
    Tan, WF
    Liu, F
    Wang, JB
    Ruan, HD
    CHEMISTRY OF MATERIALS, 2004, 16 (22) : 4330 - 4336
  • [36] Contribution of vibrational excited molecular nitrogen to ammonia synthesis using an atmospheric-pressure plasma jet
    Miyake, Atsufumi
    Shirai, Naoki
    Sasaki, Koichi
    JOURNAL OF APPLIED PHYSICS, 2024, 135 (21)
  • [37] New Design Strategy of High Efficiency Catalysis System for Ammonia Synthesis at Room Temperature and Atmospheric Pressure
    Liu Zhongfan
    ACTA PHYSICO-CHIMICA SINICA, 2019, 35 (11) : 1171 - 1172
  • [38] Electrochemical synthesis of ammonia and coproduction of metal Sulfides from hydrogen sulfide and nitrogen under atmospheric pressure
    Murakami, T
    Nohira, T
    Ogata, YH
    Ito, Y
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (06) : D109 - D112
  • [39] Preparation of double-doped BaCeO3 and its application in the synthesis of ammonia at atmospheric pressure
    Li, Zhihe
    Liu, RuiQuan
    Wang, Jide
    Xu, Zheng
    Xie, YaHong
    Wang, BenHui
    SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2007, 8 (7-8) : 566 - 570
  • [40] One-step direct ammonia synthesis by pulse-modulated microwave plasma at atmospheric pressure
    王伟
    李瑶
    陈兆权
    李思思
    冯旖
    郑直
    杨徳正
    刘悦
    Plasma Science and Technology, 2025, 27 (04) : 117 - 126