Simulation of thermodynamic properties of borosilicate melts containing alkaline-earth metal oxides

被引：5

作者：

Shilov, A. L. ^{[1
]}

Stolyarova, V. L. ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg 198504, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

SILICATE-GLASSES; SYSTEM;

D O I：

10.1134/S1070363210120030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The possibility for simulation of thermodynamic parameters of MO-B2O3-SiO2 melts (M = Ca, Sr, Ba) in terms of the UNIQUAC associated solution theory was demonstrated using the experimental data obtained previously by high-temperature mass spectrometry (1650-1800 K). The calculated numbers of different bonds formed in the examined melts were found to correlate with the deviations of their thermodynamic parameters from ideality.

引用

页码：2414 / 2424

页数：11

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