Additive-Free Ruthenium-Catalyzed Hydrogen Production from Aqueous Formaldehyde with High Efficiency and Selectivity

被引：38

作者：

Wang, Lin ^{[1
]}

Ertem, Mehmed Z. ^{[2
]}

Kanega, Ryoichi ^{[1
]}

Murata, Kazuhisa ^{[1
]}

Szalda, David J. ^{[3
]}

Muckerman, James T. ^{[2
]}

Fujita, Etsuko ^{[2
]}

Himeda, Yuichiro ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Environm & Energy Dept, Res Inst Energy Frontier, Tsukuba Cent 5,1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan

[2] Brookhaven Natl Lab, Div Chem, Upton, NY 11973 USA

[3] CUNY, Baruch Coll, Dept Nat Sci, New York, NY 10010 USA

来源：

ACS CATALYSIS | 2018年 / 8卷 / 09期

关键词：

dehydrogenation; formaldehyde; homogeneous catalysis; ruthenium complex; H-2; production; FORMIC-ACID; CO2; HYDROGENATION; METHANOL DEHYDROGENATION; HOMOGENEOUS CATALYSTS; CARBON-DIOXIDE; WATER; COMPLEX; ENERGY; LIGAND; PARAFORMALDEHYDE;

D O I：

10.1021/acscatal.8b02088

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An efficient water-soluble ruthenium complex was developed for selective hydrogen production from aqueous formaldehyde under mild conditions with a high yield (similar to 95%). Hydrogen production by this catalytic system proceeds without using any additives or organic solvents, leading to a high turnover frequency (8300 h(-1)) and a record turnover number of 24 000. Moreover, based on mechanistic experiments and density functional theory (DFT) calculations, a step-by-step mechanism has been proposed for the catalytic cycle.

引用

页码：8600 / 8605

页数：11

共 50 条

[21] Hydrogen Production from Formic Acid and Formaldehyde over Ruthenium Catalysts in Water
Patra, Soumyadip
Singh, Sanjay K.
INORGANIC CHEMISTRY, 2020, 59 (07) : 4234 - 4243
[22] Tuning the Incorporation of Magnesium into Calcite during Its Crystallization from Additive-Free Aqueous Solution
Xto, Jacinta M.
Du, Huachuan
Borca, Camelia N.
Amstad, Esther
van Bokhove, Jeroen A.
Huthwelker, Thomas
CRYSTAL GROWTH & DESIGN, 2019, 19 (08) : 4385 - 4394
[23] Ruthenium-catalyzed selective imine synthesis from nitriles and secondary alcohols under hydrogen acceptor- and base-free conditions
Kim, Daeun
Kang, Byungjoon
Hong, Soon Hyeok
ORGANIC CHEMISTRY FRONTIERS, 2016, 3 (04): : 475 - 479
[24] From a Sequential to a Concurrent Reaction in Aqueous Medium: Ruthenium-Catalyzed Allylic Alcohol Isomerization and Asymmetric Bioreduction
Rios-Lombardia, Nicolas
Vidal, Cristian
Liardo, Elisa
Moris, Francisco
Garcia-Alvarez, Joaquin
Gonzalez-Sabin, Javier
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (30) : 8691 - 8695
[25] Ruthenium-Catalyzed Enantioselective Synthesis of β-Amino Alcohols from 1,2-Diols by "Borrowing Hydrogen"
Putra, Anggi Eka
Oe, Yohei
Ohta, Tetsuo
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (27) : 6146 - 6151
[26] Covalent Triazine Framework Encapsulated Ultrafine PdAu Alloy Nanoclusters as Additive-Free Catalysts for Efficient Hydrogen Production from Formic Acid
Wang, Jiansong
Yu, Yangyang
Yu, Hui
Wang, Wei
Shen, Liu-Liu
Zhang, Gui-Rong
Mei, Donghai
ACS CATALYSIS, 2023, 13 (08) : 5135 - 5146
[27] High particulate matter emission from additive-free Natural American Spirit cigarettes
Iffland, Yvonne
Mueller, Ruth
Groneberg, David
Gerber, Alexander
SPRINGERPLUS, 2016, 5
[28] Hydrogen Production via Aqueous-Phase Reforming of Ethanol Catalyzed by Ruthenium Alkylidene Complexes
Wang, Qian
Xia, Yihao
Chen, Zhijian
Wang, Yifan
Cheng, Fanrui
Qin, Lei
Zheng, Zhiping
ORGANOMETALLICS, 2022, 41 (08) : 914 - 919
[29] Ruthenium-Catalyzed Synthesis of α-Alkylated Ketones and Quinolines in an Aqueous Medium via a Hydrogen-Borrowing Strategy Using Ketones and Alcohols
Verma, Ashutosh
Hazra, Susanta
Dolui, Pritam
Elias, Anil J.
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 10 (03) : 626 - 633
[30] CuAg nanoparticles immobilized on biomass carbon nanospheres for high-efficiency hydrogen production from formaldehyde
Feng, Tao
Meng, Xu-Feng
Gao, Shu-Tao
Feng, Cheng
Shang, Ning-Zhao
Wang, Chun
CATALYSIS COMMUNICATIONS, 2018, 113 : 10 - 14

← 1 2 3 4 5 →