Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO4

被引：35
|
作者：
Yu, Hongwei [1 ]
Cantwell, Jacqueline [2 ]
Wu, Hongping [1 ]
Zhang, Weiguo [1 ]
Poeppelmeier, Kenneth R. [2 ]
Halasyamani, P. Shiv [1 ]
机构：
[1] Univ Houston, Dept Chem, 112 Fleming Bldg, Houston, TX 77204 USA
[2] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
来源：
CRYSTAL GROWTH & DESIGN | 2016年 / 16卷 / 07期
基金：
美国国家科学基金会;
关键词：
2ND-HARMONIC GENERATION RESPONSE; BIREFRINGENT MATERIALS; PHASE-TRANSITIONS; BORATE MATERIALS; ABSORPTION-EDGE; ANIONIC GROUP; NLO CRYSTALS; DEEP; NA2TEW2O9; DESIGN;
D O I：
10.1021/acs.cgd.6b00529
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ba-3(ZnB5O10)PO4 (BZBP) single crystals were grown successfully by a top-seeded solution growth method. High-resolution X-ray diffraction rocking curve measurements reveal a full width at half-maximum of 34.56 '' of a BZBP single crystal grown from a [101]-oriented seed. The refractive indices from the UV to the near infrared region were measured, and revealed a birefringence of 0.04179-0.03059 in the wavelength range of 253.6-2325.4 nm. In addition the type-I and type-II phase-matching range for second and third harmonic generation were calculated based on the fitted Sellmeier equations. In order to further evaluate the potential application of Ba-3(ZnB5O10)PO4, the thermal properties including specific heat, thermal diffusivity, and thermal conductivity were also measured along different crystallographic axes.
引用
收藏
页码：3976 / 3982
页数：7
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