Efficient recyclable CuI-nanoparticle-catalyzed S-arylation of thiols with aryl halides on water under mild conditions

被引：85

作者：

Xu, Hua-Jian ^{[1
]}

Liang, Yu-Feng ^{[1
]}

Zhou, Xin-Feng ^{[1
]}

Feng, Yi-Si ^{[2
,3
]}

机构：

[1] Hefei Univ Technol, Sch Med Engn, Hefei 230009, Peoples R China

[2] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China

[3] Anhui Key Lab Controllable Chem React & Mat Chem, Hefei 230009, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 13期

基金：

中国国家自然科学基金;

关键词：

CROSS-COUPLING REACTIONS; BOND FORMATION; C-N; TRANSITION-METAL; DIARYL SULFIDES; COPPER; PALLADIUM; LIGAND; IODIDES; THIOETHERS;

D O I：

10.1039/c2ob06795a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

CuI nanoparticles efficiently catalyzed the C-S cross coupling of aryl and alkyl thiols with aryl halides in the absence of ligands on water under mild conditions. A wide range of diaryl sulfides and aryl alkyl sulfides are synthesized in good to excellent yields utilizing this protocol. This procedure is particularly noteworthy given its mild conditions, avoiding the undesired formation of disulfides through oxidation of thiols. The recovery and successful reutilization of the catalyst is described. Furthermore, the directed synthesis of bisarylated product is presented.

引用

页码：2562 / 2568

页数：7

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