Thermodynamic properties in gold phenylacetylide in the range 0-330 K

被引：0

作者：

Bykova, TA ^{[1
]}

Lebedev, BV ^{[1
]}

机构：

[1] NI Lobachevskii State Univ, Res Inst Chem, Nizhnii Novgorod, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2001年 / 71卷 / 02期

关键词：

Copper; Gold; Entropy; Heat Capacity; Calorimeter;

D O I：

10.1023/A:1012343203963

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature dependence of the heat capacity of gold phenylacetylide in the range 13-330 K was measured in an adiabatic vacuum calorimeter with an accuracy of similar to0.3%. These data were used for calculating the thermodynamic functions C-p(0)(T), H-0(T) - H-0(O), S-0(T) - S-0(O), and G(0)(T) - H-0(O) for the range 0-330 K. The standard entropy of formation Delta S-p(0) of gold phenylacetylide from the elements at T 298.15 K and p 101.325 kPa was calculated. The thermodynamic properties of gold phenylacetylide and related silver and copper compounds were compared.

引用

页码：213 / 216

页数：4

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