Thermodynamic properties in gold phenylacetylide in the range 0-330 K

被引:0
|
作者
Bykova, TA [1 ]
Lebedev, BV [1 ]
机构
[1] NI Lobachevskii State Univ, Res Inst Chem, Nizhnii Novgorod, Russia
关键词
Copper; Gold; Entropy; Heat Capacity; Calorimeter;
D O I
10.1023/A:1012343203963
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The temperature dependence of the heat capacity of gold phenylacetylide in the range 13-330 K was measured in an adiabatic vacuum calorimeter with an accuracy of similar to0.3%. These data were used for calculating the thermodynamic functions C-p(0)(T), H-0(T) - H-0(O), S-0(T) - S-0(O), and G(0)(T) - H-0(O) for the range 0-330 K. The standard entropy of formation Delta S-p(0) of gold phenylacetylide from the elements at T 298.15 K and p 101.325 kPa was calculated. The thermodynamic properties of gold phenylacetylide and related silver and copper compounds were compared.
引用
收藏
页码:213 / 216
页数:4
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