Two-phase (bio)catalytic reactions in a table-top centrifugal contact separator

被引：37
|
作者：
Kraai, Gerard N. [1 ]
van Zwol, Floris [1 ]
Schuur, Boelo [1 ]
Heeres, Hero J. [1 ]
de Vries, Johannes G. [2 ,3 ]
机构：
[1] Univ Groningen, Dept Chem Engn, NL-9747 AG Groningen, Netherlands
[2] DSM Pharmaceut Prod Adv Synth Catalysis & Dev, NL-6160 MD Geleen, Netherlands
[3] Univ Groningen, Dept Organ & Mol Inorgan Chem, Stratingh Inst, NL-9747 AG Groningen, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 21期
关键词：
biphasic catalysis; enzyme catalysis; esterification; fatty acids; sustainable chemistry;
D O I：
10.1002/anie.200705426
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) A new spin on catalysis: A table-top centrifugal contact separator allows for fast continuous two-phase reactions to be performed by intimately mixing two immiscible phases and then separating them. Such a device has been used to produce biodiesel from sunflower oil and MeOH/NaOMe. A lipase-catalyzed esterification of oleic acid with nBuOH (see picture) also proceeds with high conversion and can be run for up to 13 h. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：3905 / 3908
页数：4
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