Synthesis and properties of N-(2,2,2-trichloroethylidene)and N-(2,2,2-trichloroethyl)nitrobenzenesulfonamides

被引：9
|
作者：
Rozentsveig, IB [1 ]
Levkovskaya, GG [1 ]
Rybalova, TN [1 ]
Mirskova, AN [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, Irkutsk Inst Chem, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 37卷 / 01期
关键词：
Oxygen; Nitrogen; Organic Chemistry; Trichloroethylene; Nitrogen Nucleophile;
D O I：
10.1023/A:1012381602378
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly reactive N-(2,2,2-trichloroethylidene)nitrobenzenesulfonamides were synthesized by reaction of N,N-dichloronitrobenzenesulfonamides with trichloroethylene. Reactions of N-(2,2,2-trichlorocthylidene)nitrobenzenesulfonamides with oxygen and nitrogen nucleophiles gave products of addition at the double C=N bond; with arenes and haloarenes, the corresponding C-amidoalkylation products were obtained.
引用
收藏
页码：87 / 92
页数：6
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