Aryl Oligogermanes as Ligands for Transition Metal Complexes

被引：4

作者：

Zaitsev, Kirill V. ^{[1
]}

Lam, Kevin ^{[2
]}

Tafeenko, Viktor A. ^{[1
]}

Korlyukov, Alexander A. ^{[3
]}

Poleshchuk, Oleg Kh. ^{[4
,5
]}

机构：

[1] Moscow MV Lomonosov State Univ, Chem Dept, B-234 Leninskie Gory 1,3, Moscow 119991, Russia

[2] Univ Greenwich, Dept Pharmaceut Chem & Environm Sci, Chatham ME4 4TB, Kent, England

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilova Str, Moscow, Russia

[4] Natl Res Tomsk Polytech Univ, Lenin Av 30, Tomsk 634050, Russia

[5] Tomsk State Pedag Univ, Kievskaya Str 60, Tomsk 634061, Russia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 45期

关键词：

Germanium; Oligogermanes; Structure elucidation; Carbonyl ligands; Chromium; NONLINEAR-OPTICAL PROPERTIES; NUCLEAR-MAGNETIC-RESONANCE; CHROMIUM TRICARBONYL COMPLEXES; ELECTRONIC-ABSORPTION-SPECTRA; CRYSTAL-STRUCTURE; GE BOND; SI-SI; STRUCTURAL-CHARACTERIZATION; ELECTROCHEMICAL GENERATION; ORGANOMETALLIC CHEMISTRY;

D O I：

10.1002/ejic.201801095

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligand properties of a series of aryl oligogermanes R3Ge-GeAr3, 3-7 [Me3Ge-GePh3 (3), Me3Ge-Ge(pTol)(3) (4), Ph3Ge-GePh3 (5), (C6F5)(3)Ge-GePh3 (6), Ph3Ge-GeMe2GePh3 (7)] for the synthesis of transition metal carbonyl complexes such as R3Ge-GeAr2(R'C6H4-eta(6))M(CO)(3) (M = Cr, 3a-7a; M = Mo, 3b; M = W, 3c) were investigated. The target complexes were obtained in moderate yields using several different synthetic approaches. The physicochemical properties of these new derivatives were investigated by IR, UV/Vis, NMR spectroscopy, electrochemistry, and DFT calculations. The molecular structures of 3c, 4a, and 5a were studied by single-crystal X-ray diffraction analysis. A comparative analysis of donor and acceptor properties of aryl oligogermanes as ligands for transition metal carbonyl complexes is reported.

引用

页码：4911 / 4924

页数：14

共 50 条

[21] Aryl Germanes as Ligands for Transition Polymetallic Complexes: Synthesis, Structure, and Properties
Zaitsev, Kirill V.
Lam, Kevin
Poleshchuk, Oleg Kh.
Bezzubov, Stanislav I.
Churakov, Andrei V.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, (22) : 2750 - 2760
[22] Reactivity umpolung (reversal) of ligands in transition metal complexes
Morris, Robert H.
CHEMICAL SOCIETY REVIEWS, 2024, 53 (06) : 2808 - 2827
[23] TRANSITION-METAL COMPLEXES OF SYNTHETIC MACROCYCLIC LIGANDS
LINDOY, LF
CHEMICAL SOCIETY REVIEWS, 1975, 4 (03) : 421 - 441
[24] TRANSITION METAL THIOLATE AND CHLORO-COMPLEXES AS LIGANDS
JOSHI, KK
WARDLE, R
WILSON, VA
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1970, 6 (01): : 49 - &
[25] TRANSITION-METAL COMPLEXES OF UNSYMMETRICAL, BIDENTATE LIGANDS
ANDERSON, GK
LAXMAN, RK
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 120 - INOR
[26] Study of transition metal complexes of some oximic ligands
Kelkar, JG
Mehta, BH
ASIAN JOURNAL OF CHEMISTRY, 2000, 12 (02) : 412 - 416
[27] Stacking interactions of aromatic ligands in transition metal complexes
Malenov, Dusan P.
Zaric, Snezana D.
COORDINATION CHEMISTRY REVIEWS, 2020, 419
[28] TRANSITION-METAL COMPLEXES WITH TERMINAL CARBYNE LIGANDS
KIM, HP
ANGELICI, RJ
ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1987, 27 : 51 - 111
[29] DPP dyes as Ligands in transition-metal complexes
Lorenz, IP
Limmert, M
Mayer, P
Piotrowski, H
Langhals, H
Poppe, M
Polborn, K
CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (17) : 4047 - 4055
[30] INTERCONVERSION OF DIHYDROGEN AND HYDRIDE LIGANDS IN TRANSITION METAL COMPLEXES
Eckert, J.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2002, 58 : C219 - C219

← 1 2 3 4 5 →