A high-performance, durable and low-cost proton exchange membrane electrolyser with stainless steel components

被引:95
|
作者
Stiber, S. [1 ]
Sata, N. [1 ]
Morawietz, T. [1 ]
Ansar, S. A. [1 ]
Jahnke, T. [2 ]
Lee, J. K. [3 ]
Bazylak, A. [3 ]
Fallisch, A. [4 ]
Gago, A. S. [1 ]
Friedrich, K. A. [1 ,5 ]
机构
[1] German Aerosp Ctr DLR, Inst Engn Thermodynam Electrochem Energy Technol, Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany
[2] German Aerosp Ctr DLR, Inst Engn Thermodynam Computat Electrochem, Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany
[3] Univ Toronto, Inst Sustainable Energy, Fac Appl Sci & Engn, Dept Mech & Ind Engn, Toronto, ON M5S 3G8, Canada
[4] Fraunhofer Inst Solare Energiesyst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
[5] Univ Stuttgart, Inst Bldg Energet Thermal Engn & Energy Storage I, Pfaffenwaldring 31, D-70569 Stuttgart, Germany
基金
欧盟地平线“2020”;
关键词
POROUS TRANSPORT LAYER; WATER ELECTROLYSIS; BIPOLAR PLATES; DIFFUSION LAYERS; CATALYST; CELLS; GAS; DEGRADATION; TITANIUM;
D O I
10.1039/d1ee02112e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Proton exchange membrane water electrolysis (PEMWE) is the most promising technology for sustainable hydrogen production. However, it has been too expensive to compete with current state-of-the-art technologies due to the high cost of titanium bipolar plates (BPPs) and porous transport layers (PTLs). Here, we report a high-performance, durable and low-cost PEMWE cell with coated stainless steel (ss) BPPs and PTLs. When using uncoated ss components in the PEMWE cell, the cell depolarizes rapidly, reaching 2 V at only 0.15 A cm(-2). After the application of non-precious metal coatings of Ti and Nb/Ti on the ss-BPP and ss-PTL, respectively, the current density can be increased by a factor of 13 while maintaining the same performance. Extensive physical and electrochemical characterization supported by pore network modelling shows that the Nb/Ti coating on the ss-PTL leads to efficient water and gas transport at the interface with the anode. The PEMWE cell with coated ss components was evaluated in an accelerated stress test (AST) for more than 1000 h. No sign of Fe contamination in either the membrane or the electrodes is observed at the end of the test. With our results, we demonstrate that PEMWE cells can be manufactured almost entirely in ss, facilitating an unprecedented cost reduction in this technology and advancing the widespread use of green H-2.
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页码:109 / 122
页数:15
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