Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding

被引：14

作者：

Chen, Xinyue ^{[1
]}

Li, Hui ^{[1
]}

Yin, Panchao ^{[1
,2
]}

Liu, Tianbo ^{[1
]}

机构：

[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

[2] Oak Ridge Natl Lab, Neutron Sci Directorate, Chem & Engn Mat Div, Oak Ridge, TN 37831 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 28期

基金：

美国国家科学基金会;

关键词：

TRANSITION-METAL; ORGANIC HYBRID; OXIDATION; NANOPARTICLES; CATALYSTS; NANOSCALE; MONOLAYER; OXYGEN;

D O I：

10.1039/c5cc00239g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyoxometalates (POMs) covalently functionalized with methyl methacrylate groups were applied as surfactants in the emulsion polymerization reaction of styrene. Due to the copolymerization of the methyl methacrylate groups and the styrene monomers, the polyoxometalate clusters are covalently grafted onto the surface of polystyrene latex nanoparticles. Such latex particles are fully covered with catalytic POM clusters and might serve as quasi-homogeneous catalysts.

引用

页码：6104 / 6107

页数：4